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dc.contributor.author Kim, Saet Byeol -
dc.contributor.author Kim, Jeung Yoon -
dc.contributor.author Jeong, Nak Cheon -
dc.contributor.author Ok, Kang Min -
dc.date.available 2017-06-29T08:09:18Z -
dc.date.created 2017-04-20 -
dc.date.issued 2017-01 -
dc.identifier.issn 2052-1553 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/2088 -
dc.description.abstract Large single crystals of a novel lithium cobalt coordination compound, LiCo(NC5H3(CO2)2)2(H2O)2.125 [LiCo(PDC)2] were grown via a hydrothermal reaction in high yield. The electrochemical impedance spectroscopy (EIS) data measured on a large single crystal of LiCo(PDC)2 revealed very interesting anisotropic Li+ ion conductivity. The redox potential for Co3+/Co4+ observed at ca. 200 mV in the cyclic voltammogram was consistent with the electric potential where the ionic conductivity occurred. Detailed structural analysis on a series of stoichiometrically equivalent cobalt coordination compounds, ACo(PDC)2 (A = Na+, K+, and H3O+), indicated that the presence of ion channels as well as a suitable cation size is critical for the anisotropic ionic conductivity. © the Partner Organisations 2017. -
dc.language English -
dc.publisher Royal Society of Chemistry -
dc.title Anisotropic Li+ ion conductivity in a large single crystal of a Co(III) coordination complex -
dc.type Article -
dc.identifier.doi 10.1039/c6qi00314a -
dc.identifier.wosid 000393814600006 -
dc.identifier.scopusid 2-s2.0-85009350155 -
dc.identifier.bibliographicCitation Inorganic Chemistry Frontiers, v.4, no.1, pp.79 - 83 -
dc.description.isOpenAccess FALSE -
dc.subject.keywordPlus METAL-ORGANIC FRAMEWORKS -
dc.subject.keywordPlus PROTON CONDUCTIVITY -
dc.subject.keywordPlus LITHIUM BATTERIES -
dc.subject.keywordPlus PLASTIC CRYSTAL -
dc.subject.keywordPlus ELECTROLYTES -
dc.subject.keywordPlus TRANSPORT -
dc.subject.keywordPlus POLYMERS -
dc.subject.keywordPlus ENHANCEMENT -
dc.subject.keywordPlus CONDUCTORS -
dc.subject.keywordPlus CHEMISTRY -
dc.citation.endPage 83 -
dc.citation.number 1 -
dc.citation.startPage 79 -
dc.citation.title Inorganic Chemistry Frontiers -
dc.citation.volume 4 -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.relation.journalResearchArea Chemistry -
dc.relation.journalWebOfScienceCategory Chemistry, Inorganic & Nuclear -
dc.type.docType Article -
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Department of Physics and Chemistry Supramolecular Inorganic Chemistry Laboratory 1. Journal Articles

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