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Effects of TiO2:MgO-Mixed Overlayer on the Performance of Dye-Sensitized Solar Cells

Title
Effects of TiO2:MgO-Mixed Overlayer on the Performance of Dye-Sensitized Solar Cells
Authors
Park, SK[Park, Su Kyung]Lee, SW[Lee, Se Won]Sung, SJ[Sung, Shi-Joon]Lee, SH[Lee, Sung Ho]Lee, CH[Lee, Chang-Hyun]Bae, K[Bae, Kang]Kim, HM[Kim, Hwa-Min]Han, YS[Han, Yoon Soo]
DGIST Authors
Lee, SW[Lee, Se Won]
Issue Date
2016-08
Citation
Journal of Nanoscience and Nanotechnology, 16(8), 8575-8579
Type
Article
Article Type
Article
Keywords
Charge RecombinationsDye-Sensitized Solar Cells (DSCs)EfficiencyMgCl2Open Circuit VoltagePhoto-ElectrodePhoto-Injected ElectronsPhotovoltaic PerformancePower Conversion EfficienciesShort-Circuit PhotocurrentSolar CellsSolar Power GenerationSolutionsSurface ModificationSurface TreatmentTiCl4Titanium Dioxide
ISSN
1533-4880
Abstract
Photovoltaic performance of dye-sensitized solar cells (DSSCs) with a mixed overlayer composed of TiO2 and MgO was investigated in detail. The surface of photoelectrode (TiO2) films was modified with a TiCl4:MgCl2 mixed aqueous solutions with various molar ratios and then calcining to produce the surface-modified TiO2 photoelectrodes (Ti:Mg-TiO2/FTO). The highest power conversion efficiency was obtained from DSSC with Ti:Mg(3:7)-TiO2/FTO, which was prepared from the mixed solution with the molar ratio of 3:7 (TiCl4:MgCl2). An enhancement in short-circuit photocurrent (Jsc) and open-circuit voltage (Voc) of DSSC with Ti:Mg(3:7)-TiO2/FTO was achieved, compared to those of the reference device with bare TiO2/FTO. The incorporation of the mixed overlayer on the nanoporous TiO2 photoelectrode led to an improvement in both the light harvesting efficiency and the electron collection efficiency, thereby increasing the Jsc value. The increase in Voc value of the device with Ti:Mg(3:7)-TiO2/FTO was due to the reduced charge recombination between photo-injected electrons and I-3 ions. Copyright © 2016 American Scientific Publishers.
URI
http://hdl.handle.net/20.500.11750/2220
DOI
10.1166/jnn.2016.12494
Publisher
American Scientific Publishers
Files:
There are no files associated with this item.
Collection:
Convergence Research Center for Solar Energy1. Journal Articles


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