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Fabrication of Binder-Free Pencil-Trace Electrode for Lithium-Ion Battery: Simplicity and High Performance

Title
Fabrication of Binder-Free Pencil-Trace Electrode for Lithium-Ion Battery: Simplicity and High Performance
Authors
Park, HY[Park, Hyean-Yeol]Kim, MS[Kim, Min-Sik]Bae, TS[Bae, Tae-Sung]Yuan, JL[Yuan, Jinliang]Yu, JS[Yu, Jong-Sung]
DGIST Authors
Park, HY[Park, Hyean-Yeol]; Kim, MS[Kim, Min-Sik]; Yu, JS[Yu, Jong-Sung]
Issue Date
2016-05-10
Citation
Langmuir, 32(18), 4415-4423
Type
Article
Article Type
Article
Keywords
Anode Material for Lithium Ion BatteriesAnodesBindersBinsCharge Discharge CyclingCost-EffectiveCost EffectivenessElectric BatteriesElectric DischargesElectro-Chemical ElectrodesElectrochemical ReductionsElectrodesElectrolytic ReductionGrapheneHigh Reversible CapacitiesIonsLi-Ion InsertionLithiumLithium-Ion BatteriesLithium AlloysMulti-Layered GrapheneSecondary BatteriesSilicon AlloysStructural Strain
ISSN
0743-7463
Abstract
(Graph Presented) A binder-free and solvent-free pencil-trace electrode with intercalated clay particles (mainly SiO2) is prepared via a simple pencil-drawing process on grinded Cu substrate with rough surface and evaluated as an anode material for lithium-ion battery. The pencil-trace electrode exhibits a high reversible capacity of 672 mA h g-1 at 100 mA g-1 after 100 cycles, which can be attributed to the unique multilayered graphene particles with lateral size of few micrometers and the formation of LixSi alloys generated by interaction between Li+ and an active Si produced in the electrochemical reduction of nano-SiO2 in the clay particles between the multilayered graphene particles. The multilayered graphene obtained by this process consists of 1 up to 20 and occasionally up to 50 sheets and thus can not only help accommodating the volume change and alleviating the structural strain during Li ion insertion and extraction but also allow rapid access of Li ions during charge-discharge cycling. Drawing with a pencil on grinded Cu substrate is not only very simple but also cost-effective and highly scalable, easily establishing graphitic circuitry through a solvent-free and binder-free approach. © 2016 American Chemical Society.
URI
http://hdl.handle.net/20.500.11750/2686
DOI
10.1021/acs.langmuir.5b04641
Publisher
American Chemical Society
Related Researcher
  • Author Yu, Jong Sung Light, Salts and Water Research Group
  • Research Interests Materials chemistry; nanomaterials; electrochemistry; carbon and porous materials; fuel cell; battery; supercapacitor; sensor and photochemical catalyst
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Collection:
ETC1. Journal Articles


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