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Preparation and Characterization of Thermally Stable Silicon-Containing Fluoropolymer Matrix for Application to Erbium-Doped Waveguide Amplifiers
- Preparation and Characterization of Thermally Stable Silicon-Containing Fluoropolymer Matrix for Application to Erbium-Doped Waveguide Amplifiers
- Kim, WH[Kim, Wook Hyun]; Han, YS[Han, Yoon Soo]; Ma, M[Ma, Mingyang]; Kwon, Y[Kwon, Younghwan]
- DGIST Authors
- Kim, WH[Kim, Wook Hyun]
- Issue Date
- Molecular Crystals and Liquid Crystals, 618(1), 129-138
- Article Type
- Article; Proceedings Paper; Review
- Acrylic Monomers; Chemical Stability; Coupling Agents; Erbium; Erbium Doped Waveguide Amplifier; Fluorinated Acrylics; Fluorine Containing Polymers; Fluoropolymer; Fluoropolymer Matrix; Heat Resistance; High Thermal Stability; Light Amplifiers; Optical Communication; Optical Waveguide Amplifiers; Optical Waveguides; Organic Polymers; Polyhedral Oligomeric Silsesquioxanes; Polymer Films; Silane Coupling Agent; Soft Lithography; Specific Heat; Thermodynamic Stability; Waveguides
- This study focuses on the fabrication of fluoropolymer films as erbium(Er3+) host material with a goal of achieving sufficient thermal stability, optical clarity in the optical communication region and a chemical resistance to withstand typical fabrication processing and operation conditions. To satisfy the demands mentioned above, acrylo-polyhedral oligomeric silsesquioxane as heat-resistance improver, 2,2,3,3,4,4,5,5-octafluoropentyl acrylate as fluorinated acrylic monomer, tetrahydrofurfuryl acrylate as solubility enhancer, 3-(trimethoxysilyl)propyl methacrylate as both a silane coupling agent and another heat-resistance improver and Darocur 4265 as photoinitiator were used. Various compositions were evaluated to obtain high quantity of Er3+ ions in the polymer matrix, high thermal stability and high transparency. © 2015 Copyright © Taylor & Francis Group, LLC.
- Taylor and Francis Ltd.
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