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Red Phosphorescent Dopant/Polymeric Host System as an Emitting Layer: Effect of Hole Blocking Materials

Title
Red Phosphorescent Dopant/Polymeric Host System as an Emitting Layer: Effect of Hole Blocking Materials
Authors
Wang, H[Wang, Hui]Ryu, JT[Ryu, Jeong-Tak]Han, YS[Han, Yoon Soo]Kwon, Y[Kwon, Younghwan]
DGIST Authors
Han, YS[Han, Yoon Soo]
Issue Date
2009
Citation
Molecular Crystals and Liquid Crystals, 499, 340-347
Type
Article
Article Type
Article
Keywords
BathocuproineCIE CoordinatesColor PuritiesDopantElectroluminescenceEmitting LayersHigher-Energy BarriersHole-BlockingHole Blocking LayerHost PolymersIridiumIridium CompoundsLight EmissionOxadiazolePhosphorescencePhosphorescent OLEDsPL EmissionsPolymeric HostPolymersQuinolinateRed Emissions
ISSN
1542-1406
Abstract
Phosphorescent OLEDs with the configuration of ITO/PEDOT/EML/HBL/Alq3/LiF/ Al were fabricated and their electroluminescent performance was investigated. Synthesized red phosphorescent iridium (III) bis(2-phenyl-isoquinoine) (2-acetyl-cyclohexane) (Ir-PIQCH) dopant and p{[N-(2-ethylhexyl)-3,6-bis(styryl) carbazole]-alt-[2,5-(4-biphenyl)-1,3,4-oxadiazole]} [P(CZ-OXD)] host were used as emitting layer in OLEDs. The devices showed red emission (max.EL about 660nm), similar with PL emission of Ir-PIQCH dopant. EL properties of the phosphorescent OLEDs were measured to investigate the effect of hole blocking layers such as 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD), bathocuproine (BCP), and bis(2-methyl-8-quinolinate)-4-phenylphenolate (BAlq) on luminescence and color purity of the devices. It was found that Device 3 using BCP as HBL showed pure red emission with CIE coordinates value as (x=0.6673, y=0.3231), due to higher energy barrier (1.03eV) between P(CZ-OXD) host polymer and hole blocking BCP.
URI
http://hdl.handle.net/20.500.11750/3561
DOI
10.1080/15421400802618489
Publisher
Taylor and Francis Ltd.
Files:
There are no files associated with this item.
Collection:
ETC1. Journal Articles


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