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Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra

Title
Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra
Authors
Bae, JaeyeonBaek, KangkyunYuan, DaqiangKim, WooramKim, KimoonZhoue, Hong-CaiPark, Jinhee
DGIST Authors
Bae, Jaeyeon; Park, Jinhee
Issue Date
2017
Citation
Chemical Communications, 53(66), 9250-9253
Type
Article
Article Type
Article
ISSN
1359-7345
Abstract
We report a new approach for photoinduced reduction of Cu2+ that will enrich the structural diversity of coordination complexes and be a valuable contributor to the development of Cu+/Cu0-based catalysts. To realize controlled Cu2+ reduction, coumarin as a triplet quencher of excited benzophenone was tethered to Cu(ii)-metal-organic polyhedra (MOPs). The photoinduced catalytic activity of the coumarin-MOPs was also examined in a Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC). © 2017 The Royal Society of Chemistry.
URI
http://hdl.handle.net/20.500.11750/4416
DOI
10.1039/c7cc04799a
Publisher
Royal Society of Chemistry
Files:
There are no files associated with this item.
Collection:
ETC1. Journal Articles


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