Nucleophilic reactivity of copper(II)-alkylperoxo complexes
- Title
- Nucleophilic reactivity of copper(II)-alkylperoxo complexes
- Author(s)
- Kim, Bohee ; Jeong, Donghyun ; Cho, Jaeheung
- Issued Date
- 2017-08
- Citation
- Chemical Communications, v.53, no.67, pp.9328 - 9331
- Type
- Article
- Keywords
- III-OOR COMPLEXES ; O BOND-CLEAVAGE ; HIGH-SPIN IRON(III)-ALKYLPEROXO ; NONHEME IRON MODELS ; SUPEROXIDE REDUCTASE ; ELECTRONIC-STRUCTURE ; COORDINATION SPHERE ; OXIDATION ; ACTIVATION ; MECHANISM
- ISSN
- 1359-7345
- Abstract
- Copper(ii)-alkylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N′-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(ii)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. © 2017 The Royal Society of Chemistry.
- Publisher
- Royal Society of Chemistry
- Files in This Item:
-
There are no files associated with this item.
- Appears in Collections:
- Department of Physics and Chemistry Biomimetic Materials Laboratory 1. Journal Articles
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.