https://scholar.dgist.ac.kr/handle/20.500.11750/58 2026-04-04T17:06:33Z https://scholar.dgist.ac.kr/handle/20.500.11750/59007 Title: Mononuclear copper-alkylperoxo complexes in stoichiometric and catalytic reactions Author(s): Cho, Jaeheung Abstract: Mononuclear transition metal alkylperoxo complexes are important in diverse biological and catalytic oxidation processes. Among them, a number of Cu(II)-alkylperoxo species have been characterized and some of these complexes served as models of lipid peroxidation. Herein, we report the first example of Cu(II)-alkylperoxo complexes that affect aldehyde deformylation with an oxidative nucleophilic character and the kinetics of aldehyde deformylation by Cu(II)-alkylperoxo species at low temperature. The mononuclear Cu(II)-alkylperoxo complexes are characterized by various physicochemical methods such as UV-vis, CSI-MS, resonance Raman and EPR. Particularly, EPR data clearly exhibit tetragonal geometry of Cu(II)-alkylperoxo complexes, which was in good agreement with the results of DFT calculations. Interestingly, the Cu(II)-alkylperoxo complexes exhibit different reactivity at higher temperature, where the Cu(II)-alkylperoxo complexes are capable of catalyzing C-H bond activation (i.e., electrophilic reaction). 2017-08-19T15:00:00Z https://scholar.dgist.ac.kr/handle/20.500.11750/58987 Title: Mononuclear metal-O2(H) adducts in oxidative nucleophilic and electrophilic reactions Author(s): Cho, Jaeheung 2016-03-12T15:00:00Z