https://scholar.dgist.ac.kr/handle/20.500.11750/11797 Thu, 05 Nov 2026 06:43:02 GMT 2026-11-05T06:43:02Z https://scholar.dgist.ac.kr/handle/20.500.11750/61096 Title: Neutron diffraction evidence for common axial-dominant antiferromagnetic order in Fe0.7A0.3Sn (A = Co, Ni) Author(s): Park, Jaemun; Cho, Beopgil; Rhee, Taeseong; Lee, Jungmin; Kim, Jaewook; Park, Keeseong Abstract: Pristine FeSn is a kagome antiferromagnet whose ordered moments lie predominantly in the basal plane, whereas Co and Ni substitution at the Fe site has been suggested to reorient the Neel vector toward the c-axis. While the magnetic structure of Co-substituted FeSn has been investigated directly, that of Ni-substituted FeSn has remained unresolved. Here, we use neutron powder diffraction to determine the magnetic structures of polycrystalline Fe0.7Co0.3Sn and Fe0.7Ni0.3Sn. In both compounds, the absence of magnetic intensity at (0 0 1/2), together with the emergence of magnetic Bragg peaks at (1 0 1/2) and (2 0 1/2), supports predominantly axial antiferromagnetic order. Temperature-dependent diffraction further reveals subtle anomalies in the lattice parameters near the onset of magnetic intensity, suggesting a weak magnetoelastic response. Rietveld refinements at 4 K yield ordered moments of 1.26(2) mu B/(Fe, Co) and 1.12(7) mu B/(Fe, Ni) for Fe0.7Co0.3Sn and Fe0.7Ni0.3Sn, respectively, indicating suppressed long-range magnetic order relative to pristine FeSn. These results directly demonstrate that Ni substitution, like Co substitution, stabilizes a closely similar axial-dominant antiferromagnetic state in FeSn, accompanied by reduced ordered moments and suppressed ordering temperatures. Wed, 30 Sep 2026 15:00:00 GMT https://scholar.dgist.ac.kr/handle/20.500.11750/61096 2026-09-30T15:00:00Z https://scholar.dgist.ac.kr/handle/20.500.11750/60590 Title: A comparative synthesis study of α-MnTe across solid-state, Arc-melting, and Te-flux routes Author(s): Kim, Bomin; Jeong, Yunseong; Baek, Wonjung; Kim, Hobyeong; Rhee, Taeseong; Cho, Beopgil; Choi, Woo-Jae; Ha, Jae-Hyun; Park, Jaemun; Hong, Jung-Il; Kwon, Yong Seung; Seo, Jungpil; Park, Keeseong Abstract: Although alpha-MnTe has attracted renewed interest in both thermoelectric and altermagnetic contexts, direct comparisons of practically accessible synthesis routes within a common experimental framework remain limited. Here, we compare conventional solid-state reaction, arc melting and Te self-flux growth methods under a common framework of composition control and thermal history. Within the explored conditions, the phase outcome depends not only on the nominal starting composition but also on route-dependent synthesis environments, including volatilization in sealed ampoules, repeated remelting and rapid quenching in arc melting, and crystal-flux interfacial segregation in Te self-flux growth. In the solid-state route, slow heating with a slightly Mn-rich starting composition was associated with reduced MnTe2 and alpha-MnTe-dominant products. Arc melting yielded alpha-MnTe-dominant products without post-annealing, accompanied by dendritic-like microstructures. Te self-flux growth yielded single crystals, although a minor MnTe2-rich interfacial or surface layer often remained. While the present dataset does not define a rigorous phase boundary or a definitive mechanistic model, it provides a systematic comparative framework for route-dependent phase outcomes and impurity persistence in alpha-MnTe synthesis. Fri, 31 Jul 2026 15:00:00 GMT https://scholar.dgist.ac.kr/handle/20.500.11750/60590 2026-07-31T15:00:00Z https://scholar.dgist.ac.kr/handle/20.500.11750/60515 Title: Crystallographic Stability and No Evidence of Higher-Order Saddle Points in the HfFe6Ge6-type Kagome Metal ScCo6Ge6 Author(s): Park, Jaemun; Rhee, Taeseong; Cho, Beopgil; Jeong, Yunseong; Hong, Seung-Tae; Kim, Heung-Sik; Park, Keeseong Abstract: While kagome RT6X6 (R = Li, Mg, Zr, and rare-earth metals; T = 3d transition metals; X = Ge/Sn) compounds are widely studied, Co-based RCo6X6 phases remain largely limited to structural reports, with few systematic studies of their physical properties. Here we report Sn-flux-grown single-crystalline ScCo6Ge6 and its structural and physical characterization. Single-crystal X-ray diffraction confirms that ScCo6Ge6 adopts the HfFe6Ge6-type structure rather than the vacancy-driven Y0.5Co3Ge3-type variant. Across the RCo6Ge6 series, structural preference correlates with the Shannon ionic radius of R (8-fold coordination), placing ScCo6Ge6 within the stability range of the HfFe6Ge6-type framework. Magnetization exhibits weak temperature dependence consistent with Pauli-like paramagnetism. The resistivity is well described by a Bloch-Gruneisen form with a Debye temperature exceeding 230 K, consistent with phonon-dominated scattering. Electrical transport also shows a conventional linear Hall response and negligible magnetoresistance, indicative of simple metallic behavior. Electronic structure calculations identify a Ge-derived quadratic saddle point similar to 0.35 eV below E F, with no evidence of higher-order saddle points near the Fermi level. These results highlight that crystallographic stability and physical properties in RCo6Ge6 are governed not only by the Co kagome lattice but also sensitively by the Ge sublattice. Tue, 31 Mar 2026 15:00:00 GMT https://scholar.dgist.ac.kr/handle/20.500.11750/60515 2026-03-31T15:00:00Z https://scholar.dgist.ac.kr/handle/20.500.11750/60502 Title: A comparative synthesis study of α-MnTe across solid-state, Arc-melting, and Te-flux routes Author(s): Kim, Bomin; Jeong, Yunseong; Baek, Wonjung; Kim, Hobyeong; Rhee, Taeseong; Cho, Beopgil; Choi, Woo-Jae; Ha, Jae-Hyun; Park, Jaemun; Hong, Jung-Il; Kwon, Yong Seung; Seo, Jungpil; Park, Keeseong Abstract: Although alpha-MnTe has attracted renewed interest in both thermoelectric and altermagnetic contexts, direct comparisons of practically accessible synthesis routes within a common experimental framework remain limited. Here, we compare conventional solid-state reaction, arc melting and Te self-flux growth methods under a common framework of composition control and thermal history. Within the explored conditions, the phase outcome depends not only on the nominal starting composition but also on route-dependent synthesis environments, including volatilization in sealed ampoules, repeated remelting and rapid quenching in arc melting, and crystal-flux interfacial segregation in Te self-flux growth. In the solid-state route, slow heating with a slightly Mn-rich starting composition was associated with reduced MnTe2 and alpha-MnTe-dominant products. Arc melting yielded alpha-MnTe-dominant products without post-annealing, accompanied by dendritic-like microstructures. Te self-flux growth yielded single crystals, although a minor MnTe2-rich interfacial or surface layer often remained. While the present dataset does not define a rigorous phase boundary or a definitive mechanistic model, it provides a systematic comparative framework for route-dependent phase outcomes and impurity persistence in alpha-MnTe synthesis. Fri, 31 Jul 2026 15:00:00 GMT https://scholar.dgist.ac.kr/handle/20.500.11750/60502 2026-07-31T15:00:00Z