Full metadata record
DC Field | Value | Language |
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dc.contributor.author | So, Hee | - |
dc.contributor.author | Park, Young Jun | - |
dc.contributor.author | Cho, Kyung-Bin | - |
dc.contributor.author | Lee, Yong-Min | - |
dc.contributor.author | Seo, Mi Sook | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Sarangi, Ritimukta | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.available | 2017-07-05T08:52:23Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2014-09-03 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2378 | - |
dc.description.abstract | We report the first example of a mononuclear nonheme manganese(III)- hydroperoxo complex derived from protonation of an isolated manganese(III)- peroxo complex bearing an N-tetramethylated cyclam (TMC) ligand, [Mn III(TMC)(OOH)]2+. The MnIII-hydroperoxo intermediate is characterized with various spectroscopic methods as well as with density functional theory (DFT) calculations, showing the binding of a hydroperoxide ligand in an end-on fashion. The MnIII-hydroperoxo species is a competent oxidant in oxygen atom transfer (OAT) reactions, such as the oxidation of sulfides. The electrophilic character of the Mn III-hydroperoxo complex is demonstrated unambiguously in the sulfoxidation of para-substituted thioanisoles. © 2014 American Chemical Society. | - |
dc.publisher | American Chemical Society | - |
dc.title | Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)-Hydroperoxo Complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ja506275q | - |
dc.identifier.scopusid | 2-s2.0-84906860981 | - |
dc.identifier.bibliographicCitation | Journal of the American Chemical Society, v.136, no.35, pp.12229 - 12232 | - |
dc.subject.keywordPlus | SUPEROXIDE DISMUTASES | - |
dc.subject.keywordPlus | HIGH-SPIN | - |
dc.subject.keywordPlus | MANGANESE(III) COMPLEX | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURES | - |
dc.subject.keywordPlus | ATOM-TRANSFER | - |
dc.subject.keywordPlus | PEROXO | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | MECHANISMS | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | BEARING | - |
dc.citation.endPage | 12232 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 12229 | - |
dc.citation.title | Journal of the American Chemical Society | - |
dc.citation.volume | 136 | - |
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