Cited 23 time in
Cited 23 time in
Tuning glycolide as an SEI-forming additive for thermally robust Li-ion batteries
- Tuning glycolide as an SEI-forming additive for thermally robust Li-ion batteries
- Jeon, J[Jeon, Jongho]; Yoon, S[Yoon, Soojin]; Park, T[Park, Taeyoon]; Cho, JJ[Cho, Jeong-Ju]; Kang, S[Kang, Sunwoo]; Han, YK[Han, Young-Kyu]; Lee, H[Lee, Hochun]
- DGIST Authors
- Lee, H[Lee, Hochun]
- Issue Date
- Journal of Materials Chemistry, 22(39), 21003-21008
- Article Type
- Additives; Cyclability; Density Functional Theory; Electrochemical Cells; Electrochemical Experiments; Electrolyte Additives; Elevated Temperature; Functional Groups; Glycolide; Graphite; Li-Ion Batteries; Lithium-Ion Battery; Methyl Group; Seebeck Effect; Vinylene Carbonates
- A series of glycolide derivatives, glycolide (GL00), 3-methyl glycolide (GL01), 3,6-dimethyl glycolide (GL11) and 3,3,6,6-tetramethyl glycolide (GL22), are examined as SEI-forming electrolyte additives for LiCoO2/graphite lithium-ion batteries (LIBs). The novel additives are also compared with vinylene carbonate (VC), the currently most popular SEI-forming additive in LIBs. Through both density functional calculations and electrochemical experiments, it is confirmed that the number of methyl groups systematically affects anodic stability and the SEI-forming reaction of the glycolide additives. The cyclability of the LiCoO2/graphite cell is improved in the following order: VC ≥ GL00 ≥ GL01 > GL11 > GL22. With elevated temperature (90 °C) storage, however, the Al-pouch cells with VC and GL00 suffer from severe swelling, whereas the cells with GL01 and GL11 show reasonable dimensional stabilities. Both the good cyclability and the excellent thermal stability of GL01 make it the most appropriate SEI additive for the present LiCoO2/graphite chemistry. © 2012 The Royal Society of Chemistry.
- Royal Society of Chemistry
- Related Researcher
Lee, Ho Chun
Electrochemistry Laboratory for Sustainable Energy(ELSE)
Lithium-ion batteries; Novel Materials for rechargeable batteries; Novel energy conversion;storage systems; Electrochemistry; 리튬이차전지; 이차전지용 신규 전극 및 전해액; 신규 에너지변환 및 저장 시스템; 전기화학
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- Energy Science and EngineeringElectrochemistry Laboratory for Sustainable Energy(ELSE)1. Journal Articles
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