One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine
- Title
- One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine
- Author(s)
- Kang, Philjun ; Lee, Kyu Myung ; Lee, Won Koo ; Lee, Kyu Hyung ; Lee, Byeongno ; Cho, Jaeheung ; Hur, Nam Hwi
- Issued Date
- 2014-09
- Citation
- RSC Advances, v.4, no.86, pp.46203 - 46207
- Type
- Article
- Keywords
- CARBON-DIOXIDE ; PALLADIUM ; ALDEHYDES ; ESTER ; HYDROGENATION ; KETONES ; ACID ; DERIVATIVES ; HYDRAZINE ; CHLORIDE
- ISSN
- 2046-2069
- Abstract
- Many amines are liquid and their handling is inconvenient compared with the corresponding solids. We transformed a liquid (S)-(-)-1-phenylethylamine 1 to the corresponding neutral solid form 2 by reacting with carbon dioxide. We performed reductive amination of 2 with various aldehydes 3 under solvent-free conditions to provide secondary amines 5 in high yields. © 2014 the Partner Organisations.
- Publisher
- Royal Society of Chemistry
- Files in This Item:
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- Appears in Collections:
- Department of Physics and Chemistry Biomimetic Materials Laboratory 1. Journal Articles
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