Cited 33 time in webofscience Cited 34 time in scopus

Fluoropropane sultone as an SEI-forming additive that outperforms vinylene carbonate

Title
Fluoropropane sultone as an SEI-forming additive that outperforms vinylene carbonate
Authors
Jung, HM[Jung, Hyun Min]Park, SH[Park, Seong-Hyo]Jeon, J[Jeon, Jongho]Choi, Y[Choi, Yongsu]Yoon, S[Yoon, Soojin]Cho, JJ[Cho, Jeong-Ju]Oh, S[Oh, Sangdeok]Kang, S[Kang, Sunwoo]Han, YK[Han, Young-Kyu]Lee, H[Lee, Hochun]
DGIST Authors
Park, SH[Park, Seong-Hyo]; Lee, H[Lee, Hochun]
Issue Date
2013
Citation
Journal of Materials Chemistry A, 1(38), 11975-11981
Type
Article
Article Type
Article
Keywords
1,3-Propane SultoneElectrochemical ExperimentsElectron-WithdrawingElevated TemperatureLithium-Ion BatteryPropaneSeebeck EffectSolid Electrolyte InterphaseSolid ElectrolytesVinylene CarbonatesWide Temperature Ranges
ISSN
2050-7488
Abstract
Vinylene carbonate (VC) has been the best performing solid electrolyte interphase (SEI) additive for the current lithium-ion batteries (LIBs). However, it is also true that the current LIB technology is being stagnated by the limit set by VC. This study introduces 3-fluoro-1,3-propane sultone (FPS) as a novel SEI additive to replace VC and another popular SEI additive, 1,3-propane sultone (PS). Both density functional calculations and electrochemical experiments confirm that the presence of an electron withdrawing fluorine group is favourable in terms of anodic stability and SEI forming ability. In the cyclability of LiCoO2/graphite cells over a wide temperature range (25-60 °C), FPS exhibits remarkable enhancement compared with PS, and is even superior to VC. During elevated temperature (90 °C) storage of the cells, VC suffers from severe swelling, whereas FPS causes little thermal degradation. Considering the high anodic stability, the excellent cyclability, and the good thermal stability, FPS is an outstanding SEI additive that can expand the performance boundary of the current LIBs. © 2013 The Royal Society of Chemistry.
URI
http://hdl.handle.net/20.500.11750/3297
DOI
10.1039/c3ta12580g
Publisher
Royal Society of Chemistry
Related Researcher
  • Author Lee, Ho Chun Electrochemistry Laboratory for Sustainable Energy(ELSE)
  • Research Interests Lithium-ion batteries; Novel Materials for rechargeable batteries; Novel energy conversion;storage systems; Electrochemistry; 리튬이차전지; 이차전지용 신규 전극 및 전해액; 신규 에너지변환 및 저장 시스템; 전기화학
Files:
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Collection:
Energy Science and EngineeringElectrochemistry Laboratory for Sustainable Energy(ELSE)1. Journal Articles


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