Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Farha, Omar K. | ko |
dc.contributor.author | Eryazici, Ibrahim | ko |
dc.contributor.author | Jeong, Nak Cheon | ko |
dc.contributor.author | Hauser, Brad G. | ko |
dc.contributor.author | Wilmer, Christopher E. | ko |
dc.contributor.author | Sarjeant, Amy A. | ko |
dc.contributor.author | Snurr, Randall Q. | ko |
dc.contributor.author | Nguyen, SonBinh T. | ko |
dc.contributor.author | Yazaydin, A. Oezguer | ko |
dc.contributor.author | Hupp, Joseph T. | ko |
dc.date.available | 2017-07-11T06:53:19Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2012-09 | - |
dc.identifier.citation | Journal of the American Chemical Society, v.134, no.36, pp.15016 - 15021 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/3334 | - |
dc.description.abstract | We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal-organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to date (∼7000 m2/g). Key to evacuating the initially solvent-filled materials without pore collapse, and thereby accessing the ultrahigh areas, is the use of a supercritical CO2 activation technique. Additionally, we demonstrate computationally that by shifting from phenyl groups to "space efficient" acetylene moieties as linker expansion units, the hypothetical maximum surface area for a MOF material is substantially greater than previously envisioned (∼14600 m2/g (or greater) versus ∼10500 m2/g). © 2012 American Chemical Society. | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.subject | Acetylene | - |
dc.subject | Activation Techniques | - |
dc.subject | Brunauer-Emmett-Teller Surface Areas | - |
dc.subject | Carbon Dioxide | - |
dc.subject | Controlled Study | - |
dc.subject | Crystallography, X-Ray | - |
dc.subject | Java Programming Language | - |
dc.subject | Mathematical Computing | - |
dc.subject | Metal Organic Framework | - |
dc.subject | Metal Organic Framework Materials | - |
dc.subject | Models, Molecular | - |
dc.subject | Molecular Dynamics Simulation | - |
dc.subject | Molecular Structure | - |
dc.subject | Organometallic Compounds | - |
dc.subject | Phenyl Group | - |
dc.subject | Pore Collapse | - |
dc.subject | Porosity | - |
dc.subject | Porous Materials | - |
dc.subject | Space Efficient | - |
dc.subject | Supercritical CO | - |
dc.subject | Surface Area | - |
dc.subject | Surface Properties | - |
dc.subject | Surface Property | - |
dc.title | Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ja3055639 | - |
dc.identifier.wosid | 000308574800060 | - |
dc.identifier.scopusid | 2-s2.0-84866377075 | - |
dc.type.local | Article(Overseas) | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.contributor.nonIdAuthor | Farha, Omar K. | - |
dc.contributor.nonIdAuthor | Eryazici, Ibrahim | - |
dc.contributor.nonIdAuthor | Hauser, Brad G. | - |
dc.contributor.nonIdAuthor | Wilmer, Christopher E. | - |
dc.contributor.nonIdAuthor | Sarjeant, Amy A. | - |
dc.contributor.nonIdAuthor | Snurr, Randall Q. | - |
dc.contributor.nonIdAuthor | Nguyen, SonBinh T. | - |
dc.contributor.nonIdAuthor | Yazaydin, A. Oezguer | - |
dc.contributor.nonIdAuthor | Hupp, Joseph T. | - |
dc.identifier.citationVolume | 134 | - |
dc.identifier.citationNumber | 36 | - |
dc.identifier.citationStartPage | 15016 | - |
dc.identifier.citationEndPage | 15021 | - |
dc.identifier.citationTitle | Journal of the American Chemical Society | - |
dc.type.journalArticle | Article | - |
dc.description.isOpenAccess | N | - |
dc.contributor.affiliatedAuthor | Jeong, Nak Cheon | - |
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