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Highly sensitive and selective detection of Bis-phenol A based on hydroxyapatite decorated reduced graphene oxide nanocomposites

Title
Highly sensitive and selective detection of Bis-phenol A based on hydroxyapatite decorated reduced graphene oxide nanocomposites
Authors
Alam, Mohammad K.Rahman, Mohammed M.Elzwawy, AmirTorati, Sri RamuluIslam, Mohammad S.Todo, MitsuguAsiri, Abdullah M.Kim, DojinKim, CheolGi
DGIST Authors
Alam, Mohammad K.; Elzwawy, Amir; Torati, Sri Ramulu; Kim, CheolGi
Issue Date
2017-07-01
Citation
Electrochimica Acta, 241, 353-361
Type
Article
Article Type
Article
Keywords
BiocompatibilityBis Phenol ABis Phenol ABis Phenol ACarbonCell CultureChemical DetectionChemical Reduction MethodsCompositesCost EffectivenessDetection LimitDetection LimitsDifferentiationElectrochemical SensorElectrodeElectrodesExtractionFourier Transform Infrared SpectroscopyGlass Membrane ElectrodesGrapheneHigh Resolution Transmission Electron MicroscopyHuman Mesenchymal Stem CellsHydroxyapatiteLiquid ChromatographyMesenchymal Stem CellsModified Glassy Carbon ElectrodeNanocompositesNanoparticlesPhenolsReduced Graphene Oxide (RGO)Reduced Graphene Oxides (RGO)Selective Chemical SensorsSignal to Noise RatioStem CellsThermogravimetric AnalysisTransmission Electron MicroscopyTransmission Electron Microscopy ImagesWaterX Ray Diffraction
ISSN
0013-4686
Abstract
A facile and cost effective chemical reduction method is employed for the preparation of reduced graphene oxide/hydroxyapatite (rGO/HAp) nanocomposites. The transmission electron microscopy images revealed that the HAp flakes are well decorated on the surface of rGO. The morphological structure of the as-synthesized rGO/HAp nanocomposites was confirmed through X-ray diffraction, Fourier transform infrared spectroscopy and Raman spectroscopy, while the composition and thermal stability were analyzed by energy dispersive spectra and thermogravimetric analysis, respectively. Furthermore, the effect of rGO/HAp nanocomposites for the proliferation of Human Mesenchymal Stem Cell (hMSC) was performed to confirm the biocompatibility. A selective chemical sensor based on rGO/HAp modified glassy carbon electrode (GCE) for sensitive detection of Bis-phenol A (BPA) has been developed. Several important parameters controlling the performance of the BPA chemi-sensor were investigated and optimized at room conditions. The rGO/HAp/Nafion/GCE sensor offers a fast response and highly sensitive BPA detection. Under the optimal conditions, a linear range from 0.2 nmol L−1 to 2.0 mmol L−1 for the detection of BPA was observed with the detection limit of 60.0 pmol L−1 (signal-to-noise ratio, at an SNR of 3) and sensitivity of 18.98 × 104 μA.L/μmol.m2. Meanwhile, the fabricated chemi-sensor showed an excellent, specific and selective recognition to target BPA molecules among coexistence of other analytes in the buffer system. This novel effort initiated a well-organized way of efficient rGO/HAp/Nafion/GCE sensor development and practically analyzed the real hazardous environmental pollutants at room conditions. © 2017 Elsevier Ltd
URI
http://hdl.handle.net/20.500.11750/4132
DOI
10.1016/j.electacta.2017.04.135
Publisher
Elsevier Ltd
Files:
There are no files associated with this item.
Collection:
Emerging Materials ScienceLab for NanoBio-Materials & SpinTronics(nBEST)1. Journal Articles


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