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Nucleophilic reactivity of copper(II)-alkylperoxo complexes

Title
Nucleophilic reactivity of copper(II)-alkylperoxo complexes
Authors
Kim, BoheeJeong, DonghyunCho, Jaeheung
DGIST Authors
Kim, Bohee; Jeong, Donghyun; Cho, Jaeheung
Issue Date
2017
Citation
Chemical Communications, 53(67), 9328-9331
Type
Article
Article Type
Article
ISSN
1359-7345
Abstract
Copper(ii)-alkylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N′-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(ii)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. © 2017 The Royal Society of Chemistry.
URI
http://hdl.handle.net/20.500.11750/4462
DOI
10.1039/c7cc03965d
Publisher
Royal Society of Chemistry
Files:
There are no files associated with this item.
Collection:
Emerging Materials ScienceBiomimetic Materials Laboratory1. Journal Articles


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