Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Choi, Seunghyun | - |
dc.contributor.author | Kim, YunHye | - |
dc.contributor.author | Park, Bernie Byeonghoon | - |
dc.contributor.author | Park, Suzie | - |
dc.contributor.author | Park, Jonghyun | - |
dc.contributor.author | Ok, Kiwon | - |
dc.contributor.author | Koo, JaeHyung | - |
dc.contributor.author | Jung, Yong Woo | - |
dc.contributor.author | Jeon, Young Ho | - |
dc.contributor.author | Lee, Eun Hee | - |
dc.contributor.author | Lee, Ken S. | - |
dc.contributor.author | Byun, Youngjoo | - |
dc.date.available | 2017-07-05T08:51:45Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2014-11-05 | - |
dc.identifier.issn | 0022-2860 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2370 | - |
dc.description.abstract | A series of 1-aryl-3-(cyclicamino)-prop-2-en-1-one analogs was synthesized from commercial acetophenones in 2 or 3 steps. Compound 6, (E)-3-(piperidinyl)-1-(2′-hydroxyphenyl)-prop-2-en-1-one, exhibited the unique shape and intensity of the Csp2NCH2peaks in the 1H and 13C NMR spectra. Variable temperature (VT) nuclear magnetic resonance (NMR) and X-ray diffraction (XRD) studies of 6 revealed that the piperidine ring has a lower energy barrier to rotation than the 5-membered pyrrolidine 9 due to the less effective π electron delocalization along the Csp2N bond. © 2014 Elsevier B.V. All rights reserved. | - |
dc.publisher | Elsevier B.V. | - |
dc.title | X-ray diffraction and VT-NMR studies of (E)-3-(piperidinyl)-1-(2 '-hydroxyphenyl)-prop-2-en-1-one | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.molstruc.2014.08.016 | - |
dc.identifier.scopusid | 2-s2.0-84907291626 | - |
dc.identifier.bibliographicCitation | Journal of Molecular Structure, v.1076, pp.600 - 605 | - |
dc.subject.keywordAuthor | Enaminones | - |
dc.subject.keywordAuthor | X-ray diffraction | - |
dc.subject.keywordAuthor | VT-NMR | - |
dc.subject.keywordAuthor | Flexible rotation | - |
dc.subject.keywordPlus | ENAMINONES | - |
dc.subject.keywordPlus | BENZOYLACETONE | - |
dc.subject.keywordPlus | CONDENSATION | - |
dc.subject.keywordPlus | TAUTOMERISM | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | PRODUCTS | - |
dc.citation.endPage | 605 | - |
dc.citation.startPage | 600 | - |
dc.citation.title | Journal of Molecular Structure | - |
dc.citation.volume | 1076 | - |
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