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Advanced Membrane Electrode Assembly for Polymer Electrolyte Fuel cells Operated under Low Relative Humidity
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dc.contributor.advisor 상가라쥬 샨무감 -
dc.contributor.author Dabin Han -
dc.date.accessioned 2019-08-22T16:01:22Z -
dc.date.available 2019-08-22T16:01:22Z -
dc.date.issued 2019 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000220140 en_US
dc.identifier.uri http://hdl.handle.net/20.500.11750/10473 -
dc.description Polymer electrolyte fuel cells, Composite membrane, Radical scavenger, Durability, Modified catalyst layer -
dc.description.statementofresponsibility prohibition -
dc.description.tableofcontents I. Introduction
1.1 Introduction 1
1.2 Types of fuel cells 3
1.3 Polymer electrolyte fuel cell (PEFC)
1.3.1 Principle and component of PEFC 4
1.3.2 Performance of PEFC 6
1.4 Proton exchange membrane (PEM)
1.4.1 Requirements of PEM 8
1.4.2 Water management 8
1.4.3 Absorbed water in PEM 9
1.4.4 Mechanism of proton transport 9
1.4.5 Membrane degradation 11
1.4.6 The status of modification for PFSA membrane 13
1.5 Objective of research 14

II. Experimental
2.1 Pyrochlore Zirconium Gadolinium Oxide nanotubes composite membrane
2.1.1 Materials 15
2.1.2 Preparation of Zirconium-Gadolinium /PAN electrospun mat 15
2.1.3 Preparation of Zirconium-Gadolinium Oxide Nanotubes 15
2.1.4 Preparation of Nafion-ZrGdNT composite membrane 16
2.2 Modified catalyst layer containing Pyrochlore Zirconium Gadolinium Oxide nanotubes
2.2.1 Fabrication of the Nafion ionomer containing ZrGdNT 17
2.2.2 Electrochemical characterization 17
2.3 ZrGdNT Characterization 18
2.4 The membrane characterization
2.4.1 The water uptake of membrane 19
2.4.2 Measurement of ion exchange capacity 19
2.4.3 Oxidative stability investigation 19
2.4.4 Thermal gravimetric analyzer (TGA) 20
2.4.5 Tensile strength test 20
2.4.6 Proton conductivity 20
2.5 Fuel cell performance test 21

III. Results and discussion
3.1 Pyrochlore Zr2Gd2O7 nanotubes composite membrane
3.1.1 Characterization of Pyrochlore Zr2Gd2O7 nanotubes (ZrGdNT) 24
3.1.2 Characterization of Nafion ZrGdNT composite membrane 27
3.1.3 Effect of ZrGdNT 38
3.1.4 Membrane durability 41
3.2 Modified catalyst layer containing Pyrochlore Zr2Gd2O7 nanotubes
3.2.1 Modified catalyst layer with ZrGdNT 45
3.2.2 The effect of modified catalyst layer with ZrGdNT on fuel cell performance 49
3.2.3 The durability evaluation of advanced MEA 59

IV. Conclusions 62
References 64
국문 요약문 71
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dc.format.extent 83 -
dc.language eng -
dc.publisher DGIST -
dc.source /home/dspace/dspace53/upload/200000220140.pdf -
dc.subject 고분자 전해질 막 연료전지 -
dc.title Advanced Membrane Electrode Assembly for Polymer Electrolyte Fuel cells Operated under Low Relative Humidity -
dc.title.alternative Advanced Membrane Electrode Assembly for Polymer Electrolyte Fuel Cells Operated under Low Relative Humidity -
dc.type Thesis -
dc.identifier.doi 10.22677/thesis.200000220140 -
dc.description.degree Master -
dc.contributor.department Department of Energy Science and Engineering -
dc.identifier.bibliographicCitation Dabin Han. (2019). Advanced Membrane Electrode Assembly for Polymer Electrolyte Fuel cells Operated under Low Relative Humidity. doi: 10.22677/thesis.200000220140 -
dc.contributor.coadvisor Eunjoo Kim -
dc.date.awarded 2019-08 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.EM 한22 201908 -
dc.date.accepted 2019-07-01 -
dc.contributor.alternativeDepartment 에너지공학전공 -
dc.embargo.liftdate 2021-08-31 -
dc.contributor.affiliatedAuthor Shanmugam, Sangaraju -
dc.contributor.affiliatedAuthor Han, Dabin -
dc.contributor.affiliatedAuthor Kim, Eunjoo -
dc.contributor.alternativeName 한다빈 -
dc.contributor.alternativeName 김은주 -
dc.contributor.alternativeName Sangaraju Shanmugam -
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