Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes
- Title
- Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes
- Author(s)
- Bongki Shin
- DGIST Authors
- Lee, Sung Bae ; Shin, Bongki ; Cho, Jaeheung
- Advisor
- 조재흥
- Co-Advisor(s)
- Sung Bae Lee
- Issued Date
- 2019
- Awarded Date
- 2019-02
- Type
- Thesis
- Table Of Contents
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General Introduction 1
Chapter 1. A Steric Effect on the Aldehyde Deformylation Reactivity of Nickel(III)−Peroxo Complexes 19
1.1. Abstract 19
1.2. Introduction 20
1.3. Results and Discussion 22
1.4. Conclusion 45
1.5. Experimental Section 46
1.6. References 53
Chapter 2. Reactivity of a Cobalt(III)−Hydroperoxo Complex in Electrophilic Reactions 58
2.1. Abstract 58
2.2. Introduction 60
2.3. Results and Discussion 63
2.4. Conclusion 89
2.5. Experimental Section 90
2.6. References 96
Chapter 3. Characterization and Nucleophilic Reactivity of Mononuclear Cobalt(III)−Bis(tert-butylperoxo) Complex 102
3.1. Abstract 102
3.2. Introduction 103
3.3. Results and Discussion 105
3.4. Conclusion 125
3.5. Experimental Section 126
3.6. References 131
Concluding Remarks 134
Acknowledgement 136
- URI
-
http://dgist.dcollection.net/common/orgView/200000171452
http://hdl.handle.net/20.500.11750/10683
- Degree
- DOCTOR
- Department
- Emerging Materials Science
- Publisher
- DGIST
- Related Researcher
-
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Lee, Sung Bae
- Research Interests Cellular mechanism of neurodegenerative diseases; Neuronal maintenance and remodeling; 퇴행성 뇌질환의 세포기전; 신경계 유지 및 리모델링 연구
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- Appears in Collections:
- Department of Physics and Chemistry Theses Ph.D.
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