Title

Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes

DGIST Authors

Lee, Sung Bae ; Shin, Bongki ; Cho, Jaeheung

Advisor

조재흥

Co-Advisor(s)

Sung Bae Lee

Issued Date

2019

Awarded Date

2019-02

Citation

Bongki Shin. (2019). Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes. doi: 10.22677/thesis.200000171452

Type

Thesis

Table Of Contents

General Introduction 1
Chapter 1. A Steric Effect on the Aldehyde Deformylation Reactivity of Nickel(III)−Peroxo Complexes 19
1.1. Abstract 19
1.2. Introduction 20
1.3. Results and Discussion 22
1.4. Conclusion 45
1.5. Experimental Section 46
1.6. References 53
Chapter 2. Reactivity of a Cobalt(III)−Hydroperoxo Complex in Electrophilic Reactions 58
2.1. Abstract 58
2.2. Introduction 60
2.3. Results and Discussion 63
2.4. Conclusion 89
2.5. Experimental Section 90
2.6. References 96
Chapter 3. Characterization and Nucleophilic Reactivity of Mononuclear Cobalt(III)−Bis(tert-butylperoxo) Complex 102
3.1. Abstract 102
3.2. Introduction 103
3.3. Results and Discussion 105
3.4. Conclusion 125
3.5. Experimental Section 126
3.6. References 131
Concluding Remarks 134
Acknowledgement 136

URI

http://dgist.dcollection.net/common/orgView/200000171452
http://hdl.handle.net/20.500.11750/10683

DOI

10.22677/thesis.200000171452

Degree

DOCTOR

Department

Emerging Materials Science

Publisher

DGIST

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