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Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes

Title
Diverse Reactivities of Biomimetic Mononuclear Nonheme Metal−Dioxygen Complexes
Authors
Bongki Shin
DGIST Authors
Cho, Jaeheung; Shin, Bongki; Lee, Sung Bae
Advisor(s)
조재흥
Co-Advisor(s)
Sung Bae Lee
Issue Date
2019
Available Date
2019-10-03
Degree Date
2019-02
Type
Thesis
Table Of Contents
General Introduction 1 Chapter 1. A Steric Effect on the Aldehyde Deformylation Reactivity of Nickel(III)−Peroxo Complexes 19 1.1. Abstract 19 1.2. Introduction 20 1.3. Results and Discussion 22 1.4. Conclusion 45 1.5. Experimental Section 46 1.6. References 53 Chapter 2. Reactivity of a Cobalt(III)−Hydroperoxo Complex in Electrophilic Reactions 58 2.1. Abstract 58 2.2. Introduction 60 2.3. Results and Discussion 63 2.4. Conclusion 89 2.5. Experimental Section 90 2.6. References 96 Chapter 3. Characterization and Nucleophilic Reactivity of Mononuclear Cobalt(III)−Bis(tert-butylperoxo) Complex 102 3.1. Abstract 102 3.2. Introduction 103 3.3. Results and Discussion 105 3.4. Conclusion 125 3.5. Experimental Section 126 3.6. References 131 Concluding Remarks 134 Acknowledgement 136
URI
http://dgist.dcollection.net/common/orgView/200000171452
http://hdl.handle.net/20.500.11750/10683
DOI
10.22677/thesis.200000171452
Degree
DOCTOR
Department
Emerging Materials Science
University
DGIST
Related Researcher
  • Author Lee, Sung Bae Laboratory of Neurodegenerative Diseases and Aging
  • Research Interests Cellular mechanism of neurodegenerative diseases; Neuronal maintenance and remodeling; 퇴행성 뇌질환의 세포기전; 신경계 유지 및 리모델링 연구
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Collection:
Department of Emerging Materials ScienceThesesPh.D.


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