Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 조재흥 | - |
| dc.contributor.author | Youngchae Jang | - |
| dc.date.accessioned | 2019-10-02T16:02:22Z | - |
| dc.date.available | 2019-10-02T16:02:22Z | - |
| dc.date.issued | 2019 | - |
| dc.identifier.uri | http://dgist.dcollection.net/common/orgView/200000171460 | en_US |
| dc.identifier.uri | http://hdl.handle.net/20.500.11750/10714 | - |
| dc.description.statementofresponsibility | prohibition | - |
| dc.description.tableofcontents | Abstract i List of contents ii List of tables iv List of figures v Ⅰ. Introduction I. Introdiction 1 II. Experimental section 2.1 Materials and Instrumentation 3 2.2 Synthesis of Manganese complexes 4 2.2.1 [MnII(Me3-TPADP)(OTf)2] (1) 4 2.2.2 [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 5 2.2.3 [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 5 2.2.4 [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 6 2.3 Magnetic measurement 6 2.4 X-ray crystallography 7 2.5 Reactivity 10 III. Results and discussion 3.1 Synthesis of Manganese(II)-Starting Complex 10 3.2 Synthesis of Manganese(IV)-Hydroxo Complexes 13 3.3 Characterization of [MnIV(Me3-TPADP)(OH)(OCH3)]2+ (2) 13 3.4 Characterization of [MnIV(Me3-TPADP)(OH)(OC2H5)]2+ (3) 17 3.5 Characterization of [MnIV(Me3-TPADP)(OH)(OC3H7)]2+ (4) 19 3.6 Reactivity 24 3.7 Comparison of cis-effect between 2, 3 and 4 28 IV. Conclusion 4.1 Conclusion 29 |
- |
| dc.format.extent | 42 | - |
| dc.language | eng | - |
| dc.publisher | DGIST | - |
| dc.source | /home/dspace/dspace53/upload/200000171460.pdf | - |
| dc.title | Synthesis, Characterization and Reactivity of a High-valent Manganese-oxygen Complex with a Me3-TPADP ligand | - |
| dc.type | Thesis | - |
| dc.identifier.doi | 10.22677/thesis.200000171460 | - |
| dc.description.degree | MASTER | - |
| dc.contributor.department | Emerging Materials Science | - |
| dc.contributor.coadvisor | JaeHyung Koo | - |
| dc.date.awarded | 2019-02 | - |
| dc.publisher.location | Daegu | - |
| dc.description.database | dCollection | - |
| dc.citation | XT.MM 장64 201902 | - |
| dc.date.accepted | 2019-01-30 | - |
| dc.contributor.alternativeDepartment | 신물질과학전공 | - |
| dc.embargo.liftdate | 2024-02-29 | - |
| dc.contributor.affiliatedAuthor | Cho, Jaeheung | - |
| dc.contributor.affiliatedAuthor | Jang, Youngchae | - |
| dc.contributor.affiliatedAuthor | Koo, JaeHyung | - |
| dc.contributor.alternativeName | 구재형 | - |
| dc.contributor.alternativeName | 장영채 | - |
| dc.contributor.alternativeName | Jaeheung Cho | - |
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