Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Shin, Bong Ki | - |
dc.contributor.author | Park, Yeon Woo | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.date.accessioned | 2021-01-22T07:56:52Z | - |
dc.date.available | 2021-01-22T07:56:52Z | - |
dc.date.created | 2020-09-16 | - |
dc.date.issued | 2020-08 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/12845 | - |
dc.description.abstract | A mononuclear cobalt(III)-bis(tert-butylperoxo) adduct (Co-III-((OOBu)-Bu-t)(2)) bearing a tetraazamacrocyclic ligand was synthesized and characterized using various physicochemical methods, such as X-ray, UV-vis, ESI-MS, EPR, and NMR analyses. The crystal structure of the Co-III-((OOBu)-Bu-t)(2)complex clearly showed that two (OOBu)-Bu-t ligands bound to the equatorial position of the cobalt(iii) center. Kinetic studies and product analyses indicate that the Co-III-((OOBu)-Bu-t)(2)intermediate exhibits nucleophilic oxidative reactivity toward external organic substrates. | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Nucleophilic reactivity of a mononuclear cobalt(iii)-bis(tert-butylperoxo) complex | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d0cc03385e | - |
dc.identifier.scopusid | 2-s2.0-85089713028 | - |
dc.identifier.bibliographicCitation | Chemical Communications, v.56, no.66, pp.9449 - 9452 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordPlus | O BOND-CLEAVAGE | - |
dc.subject.keywordPlus | NONHEME IRON | - |
dc.subject.keywordPlus | STRUCTURAL-CHARACTERIZATION | - |
dc.subject.keywordPlus | OXIDATION ACTIVITY | - |
dc.subject.keywordPlus | OXYGEN COMPLEXES | - |
dc.subject.keywordPlus | ALKYLPEROXO | - |
dc.subject.keywordPlus | DIOXYGEN | - |
dc.subject.keywordPlus | MODELS | - |
dc.subject.keywordPlus | INTERMEDIATE | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.citation.endPage | 9452 | - |
dc.citation.number | 66 | - |
dc.citation.startPage | 9449 | - |
dc.citation.title | Chemical Communications | - |
dc.citation.volume | 56 | - |
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