DGIST Library Repository

Detail View

  Department of Physics and Chemistry Biomimetic Materials Laboratory 1. Journal Articles
Theoretical Study on the Aliphatic C-H Bond Activation by a Mononuclear Manganese(III) Iodosylbenzene Complex
Citations

WEB OF SCIENCE

Citations

SCOPUS

Metadata Downloads

XML
Excel
Title
Theoretical Study on the Aliphatic C-H Bond Activation by a Mononuclear Manganese(III) Iodosylbenzene Complex
Issued Date
2021-07
Citation
Jeong, Donghyun. (2021-07). Theoretical Study on the Aliphatic C-H Bond Activation by a Mononuclear Manganese(III) Iodosylbenzene Complex. Bulletin of the Korean Chemical Society, 42(7), 1033–1036. doi: 10.1002/bkcs.12300
Type
Article
Author Keywords
Model chemistry ; Metal‐ ; iodosylarene ; C ; H bond activation
Keywords
MULTIPLE ACTIVE OXIDANTS ; OXYGEN-ATOM TRANSFER ; ALKANE HYDROXYLATION ; HYPERVALENT IODINE ; 2-STATE REACTIVITY ; NONHEME ; IODOSYLARENE ; ADDUCTS ; OXO ; IRON(III)
ISSN
0253-2964
Abstract
We present a theoretical study on the aliphatic C-H bond activation of cyclohexadiene (CHD) by a mononuclear manganese(III) iodosylbenzene complex [Mn-III(TBDAP)(OIPh)(OH)](2+) (1). The results suggest that the first step is overall characterized as hydride transfer. However, at the more fundamental level, this step consists of a hydrogen atom transfer and a subsequent electron transfer. © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbH
URI
http://hdl.handle.net/20.500.11750/13699
DOI
10.1002/bkcs.12300
Publisher
John Wiley and Sons Inc
Show Full Item Record

File Downloads

  • There are no files associated with this item.

공유

qrcode
공유하기

Total Views & Downloads