Metal-organic framework, Open metal site, Activation of MOF, Weak coordination bonding, Paddle-wheel metal node, Hydrogen bond, Aniline oxidation, Water stable MOF; 금속유기구조체, 열린 배위자리, 금속유기구조체의 활성화, 약한 배위결합, 외륜구조 금속 노드, 수소결합, 아닐린 산화, 수분안정성
Table Of Contents
I. Introduction 1 II. Activation of Metal-organic Frameworks 6 2.1 Introduction 6 2.2 Weak coordination exchange 8 2.3 Laser activation 25 2.4 Microwave activation 32 2.5 Experimental Method and Materials 37 2.6 References 42 III. Observation of Hydrogen bonding in HKUST-1 49 3.1 Introduction 49 3.2 Result and discussion 52 3.3 Summary 70 3.4 Experimental Method 82 3.5 References 86 IV. Aniline oxidation in HKUST-1 89 4.1 Introduction 89 4.2 Result and discussion 91 4.3 Summary 101 4.4 Experimental Method 103 4.5 References 104 V. Conclusion 105