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Studies on Molecular Interaction around the Metal Node of Paddlewheel Metal-Organic Frameworks

Title
Studies on Molecular Interaction around the Metal Node of Paddlewheel Metal-Organic Frameworks
Translated Title
외륜 금속유기구조체내의 금속 노드 주변의 분자 상호작용에 대한 연구
Authors
Jinhee Bae
DGIST Authors
Jinhee Bae; Nak Cheon Jeong; Won Cheol Yoo
Advisor(s)
정낙천
Co-Advisor(s)
Won Cheol Yoo
Issue Date
2022
Available Date
2022-03-08
Degree Date
2022/02
Type
Thesis
Keywords
Metal-organic framework, Open metal site, Activation of MOF, Weak coordination bonding, Paddle-wheel metal node, Hydrogen bond, Aniline oxidation, Water stable MOF금속유기구조체, 열린 배위자리, 금속유기구조체의 활성화, 약한 배위결합, 외륜구조 금속 노드, 수소결합, 아닐린 산화, 수분안정성
Description
Metal-organic framework, Open metal site, Activation of MOF, Weak coordination bonding, Paddle-wheel metal node, Hydrogen bond, Aniline oxidation, Water stable MOF; 금속유기구조체, 열린 배위자리, 금속유기구조체의 활성화, 약한 배위결합, 외륜구조 금속 노드, 수소결합, 아닐린 산화, 수분안정성
Table Of Contents
I. Introduction 1 II. Activation of Metal-organic Frameworks 6 2.1 Introduction 6 2.2 Weak coordination exchange 8 2.3 Laser activation 25 2.4 Microwave activation 32 2.5 Experimental Method and Materials 37 2.6 References 42 III. Observation of Hydrogen bonding in HKUST-1 49 3.1 Introduction 49 3.2 Result and discussion 52 3.3 Summary 70 3.4 Experimental Method 82 3.5 References 86 IV. Aniline oxidation in HKUST-1 89 4.1 Introduction 89 4.2 Result and discussion 91 4.3 Summary 101 4.4 Experimental Method 103 4.5 References 104 V. Conclusion 105
URI
http://dgist.dcollection.net/common/orgView/200000595867
http://hdl.handle.net/20.500.11750/16329
DOI
10.22677/thesis.200000595867
Degree
Doctor
Department
Emerging Materials Science
University
DGIST
Related Researcher
  • Author Jeong, Nak Cheon Supramolecular Inorganic Chemistry Laboratory
  • Research Interests Inorganic Chemistry; Metal-Organic Framework; Nanoporous Materials; Electron Transport;Ion Transport
Files:
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Collection:
Department of Physics and ChemistryThesesPh.D.


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