Title

Studies on Molecular Interaction around the Metal Node of Paddlewheel Metal-Organic Frameworks

Alternative Title

외륜 금속유기구조체내의 금속 노드 주변의 분자 상호작용에 대한 연구

DGIST Authors

Jinhee Bae ; Nak Cheon Jeong ; Won Cheol Yoo

Advisor

정낙천

Co-Advisor(s)

Won Cheol Yoo

Issued Date

2022

Awarded Date

2022/02

Citation

Jinhee Bae. (2022). Studies on Molecular Interaction around the Metal Node of Paddlewheel Metal-Organic Frameworks. doi: 10.22677/thesis.200000595867

Type

Thesis

Subject

Metal-organic framework, Open metal site, Activation of MOF, Weak coordination bonding, Paddle-wheel metal node, Hydrogen bond, Aniline oxidation, Water stable MOF ; 금속유기구조체, 열린 배위자리, 금속유기구조체의 활성화, 약한 배위결합, 외륜구조 금속 노드, 수소결합, 아닐린 산화, 수분안정성

Description

Metal-organic framework, Open metal site, Activation of MOF, Weak coordination bonding, Paddle-wheel metal node, Hydrogen bond, Aniline oxidation, Water stable MOF; 금속유기구조체, 열린 배위자리, 금속유기구조체의 활성화, 약한 배위결합, 외륜구조 금속 노드, 수소결합, 아닐린 산화, 수분안정성

Table Of Contents

I. Introduction 1
II. Activation of Metal-organic Frameworks 6
2.1 Introduction 6
2.2 Weak coordination exchange 8
2.3 Laser activation 25
2.4 Microwave activation 32
2.5 Experimental Method and Materials 37
2.6 References 42
III. Observation of Hydrogen bonding in HKUST-1 49
3.1 Introduction 49
3.2 Result and discussion 52
3.3 Summary 70
3.4 Experimental Method 82
3.5 References 86
IV. Aniline oxidation in HKUST-1 89
4.1 Introduction 89
4.2 Result and discussion 91
4.3 Summary 101
4.4 Experimental Method 103
4.5 References 104
V. Conclusion 105

URI

http://dgist.dcollection.net/common/orgView/200000595867
http://hdl.handle.net/20.500.11750/16329

DOI

10.22677/thesis.200000595867

Degree

Doctor

Department

Emerging Materials Science

Publisher

DGIST

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