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dc.contributor.advisor 유종성 -
dc.contributor.author Tong-Hyun Kang -
dc.date.accessioned 2022-03-07T16:00:43Z -
dc.date.available 2022-03-07T16:00:43Z -
dc.date.issued 2022 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000595004 en_US
dc.identifier.uri http://hdl.handle.net/20.500.11750/16333 -
dc.description Conductive metal oxide, Magnesiothermic reduction, Heterostructure, Lithium-ion battery, Water electrolysis -
dc.description.statementofresponsibility N -
dc.description.tableofcontents Ⅰ. INTRODUCTION 1
Ⅱ. BACKGROUND 4
2.1 Lithium-ion secondary battery (LIB) 4
2.1.1 Fundamental mechanisms of LIB 5
2.1.2 Overview of anode materials for LIB 10
2.1.3 Carbon-based anode materials for LIB 12
2.1.4 Intercalation reaction-based anode materials for LIB 13
2.2 Oxygen evolution reaction (OER) 17
2.2.1 Fundamental Mechanisms of OER 17
2.2.2 Issues with conventional carbon-based for OER 19
2.2.3 Non-precious metal-based catalysts for OER 20
2.3 References 23
Ⅲ. Electrically conductive TiO with in situ grown rutile TiO2 nanothorns for lithium-ion battery anode material 26
3.1 Introduction 26
3.2 Experimental section 29
3.2.1 Preparation of porous TiO (Tx) 29
3.2.2 Synthesis of rutile TiO2 nanothorns grown TiO 29
3.2.3 Characterization 29
3.3 Results and discussion 34
3.3.1 Structural properties of as-prepared Tx and TRy 34
3.3.2 Electrochemical properties of Tx and TRy 48
3.3.3 Density functional theory analysis of electrochemical behavior 70
3.4 Conclusions 75
3.5 References 76
Ⅳ. Novel electrically conductive TiO support for facile Ni(OH)2 growth with iron(III) ions for high active and durable anode catalyst 79
4.1 Introduction 79
4.2 Experimental section 82
4.2.1 Preparation of TiO-MgO and porous TiO 82
4.2.2 Synthesis of Ni(OH)2-TiO (NiT-x) 82
4.2.3 Synthesis of Fe-activated Ni(OH)2-TiO (Fe-y-NiT-x) 83
4.2.4 Synthesis of Fe-activated Ni(OH)2-VC (Fe-y-Ni/VC) 83
4.2.5 Synthesis of RuO2/VC 83
4.2.6 Characterization 84
4.3 Results and discussion 88
4.3.1 Synthesis and characterization of NiT-x and Fe-y-NiT-x 88
4.3.2 Electrocatalytic OER performances of NiT-x 97
4.3.3 Electrocatalytic OER performances of Fe-activated Fe-y-NiT-x 98
4.3.4 Structural changes before and after Accelerated Durability Test (ADT) 104
4.4 Conclusions 112
4.5 References 113
Ⅴ. Conclusions 117
Summary (Korean) 119
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dc.format.extent 119 -
dc.language eng -
dc.publisher DGIST -
dc.subject Conductive metal oxide, Magnesiothermic reduction, Heterostructure, Lithium-ion battery, Water electrolysis -
dc.title Synthesis, Characterization and Evaluation of New Metal Oxide Materials for Energy Storage and Conversion -
dc.title.alternative 에너지 저장 및 변환 소재를 위한 새로운 종류의 금속 산화물 기반 소재의 합성, 물성 분석 및 평가 -
dc.type Thesis -
dc.identifier.doi 10.22677/thesis.200000595004 -
dc.description.degree Doctor -
dc.contributor.department Energy Science & Engineering -
dc.contributor.coadvisor Jae Hyun Kim -
dc.date.awarded 2022/02 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.ED 강25 202202 -
dc.date.accepted 1/21/22 -
dc.contributor.alternativeDepartment 에너지공학전공 -
dc.embargo.liftdate 20260228 -
dc.contributor.affiliatedAuthor Tong-Hyun Kang -
dc.contributor.affiliatedAuthor Jong-Sung Yu -
dc.contributor.affiliatedAuthor Jae Hyun Kim -
dc.contributor.alternativeName 강동현 -
dc.contributor.alternativeName Jong-Sung Yu -
dc.contributor.alternativeName 김재현 -
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