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Biomimetic Reactive Oxygen Intermediates of Manganese and Iron Complexes

Title
Biomimetic Reactive Oxygen Intermediates of Manganese and Iron Complexes
Alternative Title
망간 및 철 복합체의 생체모방 반응성 산소 중간체
Author(s)
Younwoo Park
DGIST Authors
Younwoo ParkNak Cheon JeongJaeheung Cho
Advisor
정낙천
Co-Advisor(s)
Jaeheung Cho
Issued Date
2022
Awarded Date
2022/08
Type
Thesis
Subject
Metalloenzyme, Biomimetic chemistry, Reactive metal–hydroxo species, Oxidation reactions, Bond activation
Description
Metalloenzyme, Biomimetic chemistry, Reactive metal–hydroxo species, Oxidation reactions, Bond activation
Abstract
Table Of Contents
General Introduction 1
Chapter 1. Hydrogen Atom Abstraction of Iron(III)–Hydroxide Synthetic Model Complex for the Active Site in 15-Lipoxygenase 15
1.1. Abstract 15
1.2. Introduction 16
1.3. Results and Discussion 18
1.4. Conclusion 28
1.5. Experimental Section 29
1.6. References 33
Chapter 2. Structure and Reactivity of Nonporphyrinic Terminal Manganese(IV)–Hydroxide Complexes in the Oxidative Electrophilic Reaction 39
2.1. Abstract 39
2.2. Introduction 40
2.3. Results and Discussion 42
2.4. Conclusion 92
2.5. Experimental Section 93
2.6. References 101
Concluding Remarks 110
URI
http://dgist.dcollection.net/common/orgView/200000627696

http://hdl.handle.net/20.500.11750/16776
DOI
10.22677/thesis.200000627696
Degree
Doctor
Department
Department of Physics and Chemistry
Publisher
DGIST
Related Researcher
  • 정낙천 Jeong, Nak Cheon 화학물리학과
  • Research Interests Inorganic Chemistry; Metal-Organic Framework; Nanoporous Materials; Electron Transport;Ion Transport
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Department of Physics and Chemistry Theses Ph.D.

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