Title

Biomimetic Reactive Oxygen Intermediates of Manganese and Iron Complexes

Alternative Title

망간 및 철 복합체의 생체모방 반응성 산소 중간체

DGIST Authors

Younwoo Park ; Nak Cheon Jeong ; Jaeheung Cho

Advisor

정낙천

Co-Advisor(s)

Jaeheung Cho

Issued Date

2022

Awarded Date

2022/08

Citation

Younwoo Park. (2022). Biomimetic Reactive Oxygen Intermediates of Manganese and Iron Complexes. doi: 10.22677/thesis.200000627696

Type

Thesis

Subject

Metalloenzyme, Biomimetic chemistry, Reactive metal–hydroxo species, Oxidation reactions, Bond activation

Description

Metalloenzyme, Biomimetic chemistry, Reactive metal–hydroxo species, Oxidation reactions, Bond activation

Abstract

Table Of Contents

General Introduction 1
Chapter 1. Hydrogen Atom Abstraction of Iron(III)–Hydroxide Synthetic Model Complex for the Active Site in 15-Lipoxygenase 15
1.1. Abstract 15
1.2. Introduction 16
1.3. Results and Discussion 18
1.4. Conclusion 28
1.5. Experimental Section 29
1.6. References 33
Chapter 2. Structure and Reactivity of Nonporphyrinic Terminal Manganese(IV)–Hydroxide Complexes in the Oxidative Electrophilic Reaction 39
2.1. Abstract 39
2.2. Introduction 40
2.3. Results and Discussion 42
2.4. Conclusion 92
2.5. Experimental Section 93
2.6. References 101
Concluding Remarks 110

URI

http://dgist.dcollection.net/common/orgView/200000627696
http://hdl.handle.net/20.500.11750/16776

DOI

10.22677/thesis.200000627696

Degree

Doctor

Department

Department of Physics and Chemistry

Publisher

DGIST

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