One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
- Title
- One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
- Author(s)
- Park, Changhee ; Lee, Sunggi
- Issued Date
- 2022-07
- Citation
- Bulletin of the Korean Chemical Society, v.43, no.7, pp.951 - 954
- Type
- Article
- Author Keywords
- disulfide homolysis ; pyridine-borane complex ; sulfa-Michael addition reaction ; thiyl radical ; visible light irradiation
- Keywords
- IODIDE-PROMOTED CLEAVAGE ; S-S BOND ; DIORGANYL SELENIDES ; EFFICIENT SYNTHESIS ; REDUCTION ; ALKYL ; HYDROBORATION ; DISELENIDES ; CHEMISTRY ; CATALYST
- ISSN
- 0253-2964
- Abstract
- We report a one-pot sulfa-Michael addition reaction using a disulfide and a pyridine-borane complex under blue light irradiation. This novel synthetic approach has a broad substrate scope and a high functional group tolerance. Mechanistic studies suggest that sequential radical and ionic processes provide a practical solution for constructing carbon-sulfur bonds. © 2022 Korean Chemical Society, Seoul & Wiley-VCH GmbH.
- Publisher
- Korean Chemical Society
- Related Researcher
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Lee, Sunggi
- Research Interests Organic synthesis; Catalyst development; Reaction development; Radical chemistry; Stereoselective reaction
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- Appears in Collections:
- Department of Physics and Chemistry Organic Synthesis & Catalysis Lab 1. Journal Articles
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