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One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
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- Title
- One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
- Issued Date
- 2022-07
- Citation
- Park, Changhee. (2022-07). One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation. Bulletin of the Korean Chemical Society, 43(7), 951–954. doi: 10.1002/bkcs.12574
- Type
- Article
- Author Keywords
- disulfide homolysis ; pyridine-borane complex ; sulfa-Michael addition reaction ; thiyl radical ; visible light irradiation
- Keywords
- IODIDE-PROMOTED CLEAVAGE ; S-S BOND ; DIORGANYL SELENIDES ; EFFICIENT SYNTHESIS ; REDUCTION ; ALKYL ; HYDROBORATION ; DISELENIDES ; CHEMISTRY ; CATALYST
- ISSN
- 0253-2964
- Abstract
-
We report a one-pot sulfa-Michael addition reaction using a disulfide and a pyridine-borane complex under blue light irradiation. This novel synthetic approach has a broad substrate scope and a high functional group tolerance. Mechanistic studies suggest that sequential radical and ionic processes provide a practical solution for constructing carbon-sulfur bonds. © 2022 Korean Chemical Society, Seoul & Wiley-VCH GmbH.
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- Publisher
- Korean Chemical Society
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