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  Department of Physics and Chemistry Organic Synthesis & Catalysis Lab 1. Journal Articles
One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
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Title
One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation
Issued Date
2022-07
Citation
Park, Changhee. (2022-07). One-pot sulfa-Michael addition reactions of disulfides using a pyridine-borane complex under blue light irradiation. Bulletin of the Korean Chemical Society, 43(7), 951–954. doi: 10.1002/bkcs.12574
Type
Article
Author Keywords
disulfide homolysis ; pyridine-borane complex ; sulfa-Michael addition reaction ; thiyl radical ; visible light irradiation
Keywords
IODIDE-PROMOTED CLEAVAGE ; S-S BOND ; DIORGANYL SELENIDES ; EFFICIENT SYNTHESIS ; REDUCTION ; ALKYL ; HYDROBORATION ; DISELENIDES ; CHEMISTRY ; CATALYST
ISSN
0253-2964
Abstract
We report a one-pot sulfa-Michael addition reaction using a disulfide and a pyridine-borane complex under blue light irradiation. This novel synthetic approach has a broad substrate scope and a high functional group tolerance. Mechanistic studies suggest that sequential radical and ionic processes provide a practical solution for constructing carbon-sulfur bonds. © 2022 Korean Chemical Society, Seoul & Wiley-VCH GmbH.
URI
http://hdl.handle.net/20.500.11750/17028
DOI
10.1002/bkcs.12574
Publisher
Korean Chemical Society
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