Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, K.J. | - |
dc.contributor.author | Thaheem, I. | - |
dc.contributor.author | Jeong, I. | - |
dc.contributor.author | Yu, H. | - |
dc.contributor.author | Park, J.H. | - |
dc.contributor.author | Lee, K.T. | - |
dc.date.accessioned | 2023-01-17T11:40:18Z | - |
dc.date.available | 2023-01-17T11:40:18Z | - |
dc.date.created | 2022-06-16 | - |
dc.date.issued | 2022-08 | - |
dc.identifier.issn | 0378-7753 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/17456 | - |
dc.description.abstract | Developing electrocatalysts with enhanced catalytic activities in oxygen reduction reactions (ORRs) and oxygen evolution reactions (OERs) is crucial for achieving high-performance solid oxide electrochemical cells (SOCs) at reduced temperatures. Herein, a nanostructured spinel Mn1.3Co1.3Cu0.4O4 (MCCO)-based bifunctional oxygen electrode is developed for the ORR and OER using an infiltration process. A uniform distribution and percolated network of MCCO on a Sc-stabilized ZrO2 (ScSZ) backbone without agglomeration is achieved by controlling the polymeric agent and catalyst loading. SOCs with the nanostructured MCCO-ScSZ electrode exhibited superior electrochemical performance of ∼2.2 W/cm2 in the fuel cell mode and ∼1.4 A/cm2 at 1.3 V in the electrolysis mode at 750 °C. To date, these results show the best performance for SOCs using spinel-based oxygen electrodes. Thus, our findings demonstrate that the nanoengineered MCCO catalyst has enormous potential as a bifunctional oxygen electrode for high-performance reversible SOCs at reduced temperatures. © 2022 Elsevier B.V. | - |
dc.language | English | - |
dc.publisher | Elsevier BV | - |
dc.title | Nanostructured spinel Mn1.3Co1.3Cu0.4O4 as a bifunctional electrocatalyst for high-performance solid oxide electrochemical cells at intermediate temperatures | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/j.jpowsour.2022.231611 | - |
dc.identifier.wosid | 000809626300003 | - |
dc.identifier.scopusid | 2-s2.0-85130311490 | - |
dc.identifier.bibliographicCitation | Journal of Power Sources, v.539 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordAuthor | Bifunctional catalysts | - |
dc.subject.keywordAuthor | Infiltration process | - |
dc.subject.keywordAuthor | Oxygen electrodes | - |
dc.subject.keywordAuthor | Solid oxide electrochemical cells | - |
dc.subject.keywordAuthor | Spinel oxides | - |
dc.subject.keywordPlus | OXYGEN-ELECTRODE | - |
dc.subject.keywordPlus | DOPED CERIA | - |
dc.subject.keywordPlus | FUEL-CELLS | - |
dc.subject.keywordPlus | CATHODE | - |
dc.subject.keywordPlus | CATALYST | - |
dc.subject.keywordPlus | DEGRADATION | - |
dc.citation.title | Journal of Power Sources | - |
dc.citation.volume | 539 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry; Electrochemistry; Energy & Fuels; Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Electrochemistry; Energy & Fuels; Materials Science, Multidisciplinary | - |
dc.type.docType | Article | - |
There are no files associated with this item.