Enhanced cycle stability of polypyrrole-derived nitrogen -doped carbon-coated tin oxide hollow nanofibers for lithium battery anodes

Abstract

SnO2 hollow nanofibers (SnO2 hNFs) are prepared through electrospinning and annealing processes. The polypyrrole layers coated onto the surface of the SnO2 hNFs are annealed in a nitrogen atmosphere. The nitrogen-doped carbon-coated SnO2 hNFs (SnO2/NC hNFs) are composed of SnO2 hNFs with a wall thickness of 60–80nm and a nitrogen-doped carbon layer ∼10nm thick. The nitrogen content in the carbon layer is approximately 7.95%. Owing to the nitrogen-doped carbon shell layers, the specific reversible capacity of SnO2/NC hNFs at a current density of 0.2Ag−1 after 100 cycles is 1648mAhg−1, which is 427% higher than that of (386mAhg−1) SnO2 hNFs. This strategy may open new avenues for the design of other composite architectures as electrode materials in order to achieve high-performance lithium ion batteries. © 2016 Elsevier Ltd