Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Jeong, Ah Rim | - |
dc.contributor.author | Shin, JongWon | - |
dc.contributor.author | Jeong, Jong Hwa | - |
dc.contributor.author | Bok, KwonHee | - |
dc.contributor.author | Kim, Cheal | - |
dc.contributor.author | Jeong, Donghyun | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Hayami, Shinya | - |
dc.contributor.author | Min, Kil Sik | - |
dc.date.available | 2017-06-29T08:08:43Z | - |
dc.date.created | 2017-04-20 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2078 | - |
dc.description.abstract | Dinuclear FeIII and NiII complexes, [(phenO)Fe(N3)]2(NO3)2 (1) and [(phenOH)Ni(N3)2]2 (2), were prepared by treating Fe(NO3)3?9 H2O and Ni(NO3)2?6 H2O in methanol, respectively, with phenOH (=N-(2-pyridylmethyl)-N-(2-hydroxyethyl)ethylenediamine) and NaN3; both 1 and 2 were characterized by elemental analysis, IR spectroscopy, X-ray diffraction, and magnetic susceptibility measurements. Two ethoxo-bridged FeIII and two azido-bridged NiII were observed in 1 and 2, respectively; corresponding antiferromagnetic interaction via the bridged ethoxo groups and strong ferromagnetic coupling via the bridged end-on azido ligands within the dimeric unit were observed. Complex 1 did not exhibit any catalytic activity, while 2 exhibited excellent catalytic activities for the epoxidation of aliphatic, aromatic, and terminal olefins. ? 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.publisher | Wiley-VCH Verlag | - |
dc.title | Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N′-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/chem.201604498 | - |
dc.identifier.scopusid | 2-s2.0-85012095903 | - |
dc.identifier.bibliographicCitation | Chemistry - A European Journal, v.23, no.13, pp.3023 - 3033 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordAuthor | catalysis | - |
dc.subject.keywordAuthor | coordination complexes | - |
dc.subject.keywordAuthor | crystal structure | - |
dc.subject.keywordAuthor | magnetic properties | - |
dc.subject.keywordAuthor | tetradentate ligands | - |
dc.subject.keywordPlus | TRANSITION-METAL-COMPLEXES | - |
dc.subject.keywordPlus | INDUCED ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | TERMINAL OLEFINS | - |
dc.subject.keywordPlus | ALKANE-HYDROXYLATION | - |
dc.subject.keywordPlus | NI-II | - |
dc.subject.keywordPlus | ALKENE EPOXIDATION | - |
dc.subject.keywordPlus | HYDROGEN-PEROXIDE | - |
dc.subject.keywordPlus | SPIN-CROSSOVER | - |
dc.subject.keywordPlus | M-CPBA | - |
dc.citation.endPage | 3033 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 3023 | - |
dc.citation.title | Chemistry - A European Journal | - |
dc.citation.volume | 23 | - |
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