The plasticized polymer PVdF-HFP was taken as the host and blended with 5 wt % of PEMA. The effect of blending with respect to structural, vibrational and electrical properties was studied. Blending PEMA with plasticized polymer PVdF-HFP was found to successfully enhance the film flexibility and conductivity. The dielectric spectra show an increase in side chain movement after blending.