Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Johnson, GE[Johnson, Grant E.] | ko |
dc.contributor.author | Colby, R[Colby, Robert] | ko |
dc.contributor.author | Engelhard, M[Engelhard, Mark] | ko |
dc.contributor.author | Moon, D[Moon, Daewon] | ko |
dc.contributor.author | Laskin, J[Laskin, Julia] | ko |
dc.date.available | 2017-07-05T08:51:03Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Nanoscale, v.7, no.29, pp.12379 - 12391 | - |
dc.identifier.issn | 2040-3364 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/2360 | - |
dc.description.abstract | Magnetron sputtering of two independent Pt and Ru targets coupled with inert gas aggregation in a modified commercial source has been combined with soft landing of mass-selected ions to prepare bare 4.5 nm diameter PtRu nanoparticles on glassy carbon electrodes with controlled size and morphology for electrochemical reduction of oxygen in solution. Employing atomic force microscopy (AFM) it is shown that the nanoparticles bind randomly to the glassy carbon electrode at a relatively low coverage of 7 × 104 ions μm-2 and that their average height is centered at 4.5 nm. Scanning transmission electron microscopy images obtained in the high-angle annular dark field mode (HAADF-STEM) further confirm that the soft-landed PtRu nanoparticles are uniform in size. Wide-area scans of the electrodes using X-ray photoelectron spectroscopy (XPS) reveal the presence of both Pt and Ru in atomic concentrations of ∼9% and ∼33%, respectively. Deconvolution of the high energy resolution XPS spectra in the Pt 4f and Ru 3d regions indicates the presence of both oxidized Pt and Ru. The substantially higher loading of Ru compared to Pt and enrichment of Pt at the surface of the nanoparticles is confirmed by wide-area analysis of the electrodes using time-of-flight medium energy ion scattering (TOF-MEIS) employing both 80 keV He+ and O+ ions. The activity of electrodes containing 7 × 104 ions μm-2 of bare 4.5 nm PtRu nanoparticles toward the electrochemical reduction of oxygen was evaluated employing cyclic voltammetry (CV) in 0.1 M HClO |
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dc.publisher | Royal Society of Chemistry | - |
dc.subject | Agglomeration | - |
dc.subject | Atomic Force Microscopy | - |
dc.subject | Cyclic Voltammetry | - |
dc.subject | D Region | - |
dc.subject | Diamond Films | - |
dc.subject | Electro-Chemical Electrodes | - |
dc.subject | Electrochemical Behaviors | - |
dc.subject | Electrochemical Cycling | - |
dc.subject | Electrochemical Reductions | - |
dc.subject | Electrodes | - |
dc.subject | Electrolytic Reduction | - |
dc.subject | Experimental Parameters | - |
dc.subject | Glass | - |
dc.subject | Glass Membrane Electrodes | - |
dc.subject | Glassy Carbon | - |
dc.subject | Glassy Carbon Electrodes | - |
dc.subject | High-Angle Annular Dark Fields | - |
dc.subject | High Resolution Transmission Electron Microscopy | - |
dc.subject | Ionization of Gases | - |
dc.subject | Ions | - |
dc.subject | Landing | - |
dc.subject | Medium Energy Ion Scattering | - |
dc.subject | Nanoparticles | - |
dc.subject | Oxygen | - |
dc.subject | Platinum | - |
dc.subject | Platinum Alloys | - |
dc.subject | Reduction | - |
dc.subject | Scanning Electron Microscopy | - |
dc.subject | Scanning Transmission Electron Microscopy | - |
dc.subject | Synthesis (Chemical) | - |
dc.subject | Transmission Electron Microscopy | - |
dc.subject | X Ray Photoelectron Spectroscopy | - |
dc.title | Soft landing of bare PtRu nanoparticles for electrochemical reduction of oxygen | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c5nr03154k | - |
dc.identifier.wosid | 000358207700019 | - |
dc.identifier.scopusid | 2-s2.0-84937555720 | - |
dc.type.local | Article(Overseas) | - |
dc.type.rims | ART | - |
dc.description.journalClass | 1 | - |
dc.contributor.nonIdAuthor | Johnson, GE[Johnson, Grant E.] | - |
dc.contributor.nonIdAuthor | Colby, R[Colby, Robert] | - |
dc.contributor.nonIdAuthor | Engelhard, M[Engelhard, Mark] | - |
dc.contributor.nonIdAuthor | Laskin, J[Laskin, Julia] | - |
dc.identifier.citationVolume | 7 | - |
dc.identifier.citationNumber | 29 | - |
dc.identifier.citationStartPage | 12379 | - |
dc.identifier.citationEndPage | 12391 | - |
dc.identifier.citationTitle | Nanoscale | - |
dc.type.journalArticle | Article | - |
dc.contributor.affiliatedAuthor | Moon, D[Moon, Daewon] | - |
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