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Spectrophotometric and Electrochemical Study of Cu2+-Selective Azocalix[4]arene Bearing p-Carboxyl group
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- Title
- Spectrophotometric and Electrochemical Study of Cu2+-Selective Azocalix[4]arene Bearing p-Carboxyl group
- Issued Date
- 2013-11
- Citation
- Kim, Tae Hyun. (2013-11). Spectrophotometric and Electrochemical Study of Cu2+-Selective Azocalix[4]arene Bearing p-Carboxyl group. doi: 10.5012/bkcs.2013.34.11.3377
- Type
- Article
- Article Type
- Article
- Subject
- Azo-Calix[4]Arene ; Azocalixarene ; Colorimetry ; Copper Ion ; Copper Ions ; Electrochemical Studies ; High Selectivity ; Hypsochromic Shifts ; Metal Ions ; Spectrophotometers ; Spectrophotometry ; Ultraviolet Visible Spectroscopy ; UV-Visible Spectroscopy ; Voltammetric Measurements ; Voltammetry
- ISSN
- 0253-2964
- Abstract
-
The spectrophotometric and electrochemical properties of tetraazo(p-carboxy)phenylcalix[4]arene (p-CAC) in the presence of various metal ions were investigated by UV/Vis spectroscopy and voltammetry in CH3CN. p- CAC showed selective color changes to Cu2+ over other metal ions from light orange to colorless, in accordance with hypsochromic shift in UV/Vis spectra. Voltammetric measurements also showed high selectivity for Cu2+.
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- Publisher
- Korean Chemical Society
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