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Conductive framework supported high rate performance of SnO2 hollow nanofibers for lithium battery anodes

Title
Conductive framework supported high rate performance of SnO2 hollow nanofibers for lithium battery anodes
Author(s)
Pham-Cong, DeKim, Ji YoonPark, Jung SooKim, Jae HyunKim, Jong-PilJeong, Euh-DuckKim, JinwooJeong, Se-YoungCho, Chae-Ryong
Issued Date
2015-04-10
Citation
Electrochimica Acta, v.161, pp.1 - 9
Type
Article
Author Keywords
hollow nanofiberscarbon cappinggraphene wrappingSnO2
Keywords
Average CapacitiesCarbonCarbon CappingCOAXIAL NANOCABLESDEPOSITIONElectric BatteriesElectrochemical PropertiesElectrodeElectrolyte Blocking LayersElectrostaticsGrapheneGRAPHENE COMPOSITEGraphene WrappingHigh-Rate PerformanceHigh Lithium StoragesHollow NanofibersION BATTERIESIRREVERSIBLE CAPACITIESLithiumLithium BatteriesLithium Battery AnodeMICROSPHERESNanofibersNANOPARTICLESSnO2STORAGEStructural Feature
ISSN
0013-4686
Abstract
We synthesized an electrospun SnO2 hollow nanofibers (SnO2 hNFs) coated with carbon and wrapped with graphene oxide layer by simple hydrothermal and electrostatic force method, respectively. Thin carbon layer as electrolyte blocking layer was formed on the SnO2 hNFs by using glucose as a carbon source (SnO2@C hNFs). Also, layers of graphene oxide are wrapped on SnO2@C hNFs by the electrostatic interaction force (SnO2@C@G hNFs). At high C rate, the average capacity of the SnO2@C@G hNFs still kept high capacity comparing with the SnO2 hNFs and SnO2@C hNFs and then increased above 250% at 3 C. It also exhibits a greatly enhanced synergic effect with an extremely high lithium storage capability up to 1,600 mA h g-1 and kept 900 mA h g-1 after 50 cycles benefiting from the advanced structural features. © 2015 Elsevier Ltd. All rights reserved.
URI
http://hdl.handle.net/20.500.11750/2600
DOI
10.1016/j.electacta.2015.02.001
Publisher
Elsevier Ltd
Related Researcher
  • 김재현 Kim, Jae Hyun
  • Research Interests 에너지; 배터리; 고체전해질; 태양전지; 전기차; 리튬이온배터리
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Division of Energy & Environmental Technology 1. Journal Articles

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