Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Kang, Hyeona | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Cho, Kyung-Bin | - |
dc.contributor.author | Nomura, Takashi | - |
dc.contributor.author | Ogura, Takashi | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.available | 2017-07-11T06:32:39Z | - |
dc.date.created | 2017-04-10 | - |
dc.date.issued | 2013-10 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/3189 | - |
dc.description.abstract | Mononuclear MnIII-peroxo and dinuclear bis(μ-oxo)Mn III 2 complexes that bear a common macrocyclic ligand were synthesized by controlling the concentration of the starting MnII complex in the reaction of H2O2 (i.e., a Mn III-peroxo complex at a low concentration (≤ 1 mM) and a bis(μ-oxo)MnIII 2 complex at a high concentration (≥30mM)). These intermediates were successfully characterized by various physicochemical methods such as UV-visible spectroscopy, ESI-MS, resonance Raman, and X-ray analysis. The structural and spectroscopic characterization combined with density functional theory (DFT) calculations demon-strated unambiguously that the peroxo ligand is bound in a side-on fashion in the MnIII-peroxo complex and the Mn2O2 diamond core is in the bis(μ-oxo)MnIII 2 complex. The reactivity of these intermediates was investigated in electrophilic and nucleophilic reactions, in which only the MnIII-peroxo complex showed a nucleophilic reactivity in the deformylation of aldehydes. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA. | - |
dc.publisher | Wiley-VCH Verlag | - |
dc.title | Mononuclear Manganese-Peroxo and Bis(mu-oxo)dimanganese Complexes Bearing a Common N-Methylated Macrocyclic Ligand | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/chem.201301641 | - |
dc.identifier.scopusid | 2-s2.0-84885582699 | - |
dc.identifier.bibliographicCitation | Chemistry: A European Journal, v.19, no.42, pp.14119 - 14125 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordAuthor | bioinorganic chemistry | - |
dc.subject.keywordAuthor | kinetics | - |
dc.subject.keywordAuthor | manganese | - |
dc.subject.keywordAuthor | peroxo ligands | - |
dc.subject.keywordAuthor | aldehyde deformylation | - |
dc.subject.keywordPlus | DIOXYGEN ACTIVATION | - |
dc.subject.keywordPlus | STRUCTURAL-CHARACTERIZATION | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURES | - |
dc.subject.keywordPlus | LOW-TEMPERATURE | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | OXO | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | NICKEL | - |
dc.subject.keywordPlus | COPPER | - |
dc.subject.keywordPlus | CORE | - |
dc.citation.endPage | 14125 | - |
dc.citation.number | 42 | - |
dc.citation.startPage | 14119 | - |
dc.citation.title | Chemistry: A European Journal | - |
dc.citation.volume | 19 | - |
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