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Au@Pd core-shell nanocubes with finely-controlled sizes

Title
Au@Pd core-shell nanocubes with finely-controlled sizes
Author(s)
Kim, Do YoubChoi, Kyeong WooZhong, Xiao-LanLi, Zhi-YuanIm, Sang HyukPark, O. Ok
Issued Date
2013-05
Citation
CrystEngComm, v.15, no.17, pp.3385 - 3391
Type
Article
Keywords
HIGH-INDEX FACETSSHAPE-CONTROLLED SYNTHESISWELL-CONTROLLED SIZESMETAL NANOCRYSTALSOPTICAL-PROPERTIESFORMIC-ACIDBIMETALLIC NANOPARTICLESHETEROEPITAXIAL GROWTHCATALYTIC-ACTIVITYPALLADIUM
ISSN
1466-8033
Abstract
We report a facile method for the synthesis of highly uniform Au@Pd core-shell nanocubes with finely- and well-controlled sizes by seed-mediated growth. Using single-crystal seeds of Au spheres with a uniform size, we could reproducibly obtain Au@Pd core-shell nanocubes with a narrow size distribution (<7% in standard deviation) and in high yield (>98%). Moreover, the size of the Au@Pd core-shell nanocubes could be finely and readily tuned in a controllable fashion from 11.4 to 41.1 nm in edge length by varying the concentration of Na2PdCl4, the amount of seeds, or both. We have also investigated the localized surface plasmon resonance properties of Au@Pd core-shell nanocubes as a function of Pd shell thickness. © 2013 This journal isThe Royal Society of Chemistry.
URI
http://hdl.handle.net/20.500.11750/3303
DOI
10.1039/c3ce40175h
Publisher
Royal Society of Chemistry
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Appears in Collections:
ETC 1. Journal Articles
Department of Energy Science and Engineering ETC 1. Journal Articles

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