Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kim, Bohee | - |
| dc.contributor.author | Jeong, Donghyun | - |
| dc.contributor.author | Cho, Jaeheung | - |
| dc.date.available | 2017-09-11T09:29:14Z | - |
| dc.date.created | 2017-09-11 | - |
| dc.date.issued | 2017-08 | - |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | http://hdl.handle.net/20.500.11750/4462 | - |
| dc.description.abstract | Copper(ii)-alkylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N′-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(ii)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. © 2017 The Royal Society of Chemistry. | - |
| dc.language | English | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.title | Nucleophilic reactivity of copper(II)-alkylperoxo complexes | - |
| dc.type | Article | - |
| dc.identifier.doi | 10.1039/c7cc03965d | - |
| dc.identifier.scopusid | 2-s2.0-85027550211 | - |
| dc.identifier.bibliographicCitation | Chemical Communications, v.53, no.67, pp.9328 - 9331 | - |
| dc.description.isOpenAccess | FALSE | - |
| dc.subject.keywordPlus | III-OOR COMPLEXES | - |
| dc.subject.keywordPlus | O BOND-CLEAVAGE | - |
| dc.subject.keywordPlus | HIGH-SPIN IRON(III)-ALKYLPEROXO | - |
| dc.subject.keywordPlus | NONHEME IRON MODELS | - |
| dc.subject.keywordPlus | SUPEROXIDE REDUCTASE | - |
| dc.subject.keywordPlus | ELECTRONIC-STRUCTURE | - |
| dc.subject.keywordPlus | COORDINATION SPHERE | - |
| dc.subject.keywordPlus | OXIDATION | - |
| dc.subject.keywordPlus | ACTIVATION | - |
| dc.subject.keywordPlus | MECHANISM | - |
| dc.citation.endPage | 9331 | - |
| dc.citation.number | 67 | - |
| dc.citation.startPage | 9328 | - |
| dc.citation.title | Chemical Communications | - |
| dc.citation.volume | 53 | - |
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