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Electrochemical mediatorless detection of norepinephrine based on MoO3 nanowires

Title
Electrochemical mediatorless detection of norepinephrine based on MoO3 nanowires
Authors
Samdani, Kunda J.Joh, Dong WooRath, Manas K.Lee, Kang Taek
DGIST Authors
Samdani, Kunda J.; Joh, Dong Woo; Rath, Manas K.; Lee, Kang Taek
Issue Date
2017
Citation
Electrochimica Acta, 252, 268-274
Type
Article
Article Type
Article
Keywords
Ascorbic-AcidBio-ElectrochemicalBiosensorsCarbonCarbon NanotubeCatalyst ActivityChemical DetectionChemiluminescence DetectionChronoamperometryChronoamperometry TechniquesCyclic VoltammetryDeterminationDirect Electron TransferElectrocatalytic OxidationElectrochemical BiosensorElectrochemical DetectionElectrodesElectron Transport PropertiesEpinephrineFolic-AcidGlass Membrane ElectrodesGlassy Carbon ElectrodesHeterogeneous Rate ConstantLiquid-ChromatographyMediatorlessMediator-LessMolybdenum OxideMoO3 NanowiresNanotube Paste ElectrodeNanowiresNorepinephrineRate ConstantsSensorVoltammetric
ISSN
0013-4686
Abstract
Achieving direct electron transfer between a biomolecule and modified electrodes is paramount for fabricating advanced biosensor devices. In this report, 1-dimensional (1D) MoO3 nanowires (NWs) were synthesized in a systematic growth evolution study. These MoO3 NWs, with the glassy carbon electrodes (GCEs), were further used as a mediatorless biosensor electrode for the detection of norepinephrine (NE) by cyclic voltammetry and chronoamperometry techniques. The MoO3 NWs/GCE had a magnificent response time of 2 s in the electrochemical detection of NE, with a detection limit of 0.11 μM. This excellent bio-electrochemical performance is attributed to its high catalytic activity and 1D microstructure, providing a path for electron transport and increasing their sensitivity. The MoO3 NWs/GCE also had a promising diffusion constant (D) value of 3.34 × 10−5 cm2/s and a heterogeneous rate constant (k) of 8.03 × 10−4 cm/s. The modified electrode possessed high stability, reproducibility, and selectivity. © 2017 Elsevier Ltd
URI
http://hdl.handle.net/20.500.11750/4552
DOI
10.1016/j.electacta.2017.08.187
Publisher
Elsevier Ltd
Related Researcher
  • Author Lee, Kang Taek AECSL(Advanced Energy Conversion and Storage Lab)
  • Research Interests Advanced energy conversion and storage systems; Solid-state Electrochemical Energy Devices; All solid-state batteries; low-temperature solid oxide fuel cells(SOFCs); 신 에너지 변환 및 저장 시스템; Solid-state Electrochemical Energy Devices; 차세대 전고체 이차전지(solid-state batteries) 및 저온화 고체산화물 연료전지(LT-SOFCs)
Files:
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Collection:
Department of Energy Science and EngineeringAECSL(Advanced Energy Conversion and Storage Lab)1. Journal Articles


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