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Study of Thermal Annealing Process Effect on PbS Colloidal Quantum Dot Solar Cells

Title
Study of Thermal Annealing Process Effect on PbS Colloidal Quantum Dot Solar Cells
Alternative Title
열처리 공정 개질이 황화납 콜로이드 양자점 표면 및 태양전지에 미치는 영향 연구
Author(s)
Eonji Lee
DGIST Authors
Eonji LeeJongmin ChoiDae-Hyun Nam
Advisor
최종민
Co-Advisor(s)
Dae-Hyun Nam
Issued Date
2023
Awarded Date
2023-02-01
Type
Thesis
Description
Solar cell, PbS colloidal quantum dot, Flash lamp annealing, Hydroxylation, Oxidation
Table Of Contents
Ⅰ. Introduction 1
1.1 Solar Cells for Renewable Energy Harvesting 1
1.2 Emergence of the Colloidal Quantum Dot Solar Cells 1
1.3 Lead Sulfide Colloidal Quantum Dot Solar Cells 2
1.4 Limited Photovoltaic Performance Derived from Incomplete Surface Chemistry of the PbS QD 2
1.5 PbS QD Film Annealing Process 3
1.6 Recent Research Trend of Short-Time Annealing on the PbS QD Film 3
1.7 New Approach Method using FLA in the PbS CQDSCs 4
Ⅱ. Experimental 5
2.1 Synthesis of OA-capped PbS Colloidal Quantum Dot 5
2.2 Ligand Exchange Step for CQD Ink 5
2.3 CQD Solar Cell Device Fabrication 6
2.4 Device Characterization of PbS CQD 7
2.5 Solar Cell Measurement 7
Ⅲ. Results and discussion 8
3.1 The Formation of Pb-OH and Pb-O Species on the PbS QD Films 8
3.2 The HA and FLA Annealing Process and Optimization of Annealing Conditions 8
3.2.1 Process of the HA and FLA Treatments 8
3.2.2 Optimization of the Energy Density through the PCE and Film Contraction 11
3.3 The Analysis of the Effect of the Hydroxylation and Oxidation on the PbS QD Sur-face 14
3.4 Electrical Properties of the PbS QD Films 16
3.5 Solar Cell Structure and Performance 20
Ⅳ. Conclusion 26
Ⅴ. Reference 27
VI. 요약문 30
URI
http://hdl.handle.net/20.500.11750/45736

http://dgist.dcollection.net/common/orgView/200000656618
DOI
10.22677/THESIS.200000656618
Degree
Master
Department
Department of Energy Science and Engineering
Publisher
DGIST
Related Researcher
  • 최종민 Choi, Jongmin
  • Research Interests Advanced Metal Oxides; Colloidal Quantum Dots; Perovskite-Quantum Dot Hybrid Nanomaterials; Photocatalytic Materials
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Department of Energy Science and Engineering Theses Master

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