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Hydrohalic acid-assisted Li surface modification for rechargeable Li-metal batteries

Title
Hydrohalic acid-assisted Li surface modification for rechargeable Li-metal batteries
Alternative Title
리튬 금속전지 내 할로겐화 수소산을 이용한 리튬 표면 개질
Author(s)
Jaeho Lee
DGIST Authors
Jaeho LeeHonhkyung LeeYong Min Lee
Advisor
이홍경
Co-Advisor(s)
Yong Min Lee
Issued Date
2023
Awarded Date
2023-02-01
Type
Thesis
Description
Li-metal batteries, surface modification, halogenated artificial SEI, interface analysis
Table Of Contents
Ⅰ. Introduction 1
1.1. Basic principles 1
1.2. Next Generation Batteries 2
1.2.1. Historical Background 3
1.2.2. Superiority of LMBs 4
1.2.3. Challenges of LMAs 5
1.3. Surface-deterministic Li electroplating 7
1.3.1. Li Native layer 8
1.3.2. Solid-Electrolyte interphase 9
1.3.3. Halogenated SEI 10
1.4. Surface Modification 11
1.4.1. Mechanical modifications 12
1.4.2. Chemical modifications 12
1.5. Research Goals 13
Ⅱ. Experimental Method 14
2.1. Preparation of Li-metal Treatment 14
2.2. Electrochemical measurements 14
2.3. Characterizations 15
Ⅲ. Results and discussion 16
3.1 Investigation of Li surfaces tailored by hydrohalic acids 16
3.2 Impact of Halogenated artificial SEI 22
IV. Conclusion 28
References 29
Summary in Korean 36
URI
http://hdl.handle.net/20.500.11750/45737

http://dgist.dcollection.net/common/orgView/200000658340
DOI
10.22677/THESIS.200000658340
Degree
Master
Department
Department of Energy Science and Engineering
Publisher
DGIST
Related Researcher
  • 이홍경 Lee, Hongkyung
  • Research Interests Batteries; Electrochemistry; Interfaces
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Department of Energy Science and Engineering Theses Master

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