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Enhancing Interfacial Stability of LiNi0.8Co0.1Mn0.1O2 for All-Solid-State-Batteries via Halide Coating

Title
Enhancing Interfacial Stability of LiNi0.8Co0.1Mn0.1O2 for All-Solid-State-Batteries via Halide Coating
Alternative Title
할라이드 코팅으로 전고체 전지용 NCM 계면 안정성 향상
Author(s)
Hyohyun Cha
DGIST Authors
Hyohyun ChaJong-Won LeeJong-Soo Lee
Advisor
이종원
Co-Advisor(s)
Jong-Soo Lee
Issued Date
2023
Awarded Date
2023-02-01
Type
Thesis
Description
"all-solid-state batteries", "sulfide solid-state electrolytes", "halide coating", "interfacial resistances", "chemical reactions"
Table Of Contents
Ⅰ. Introduction 1
Ⅱ. Literature survey 4
2.1 Sulfide solid-state electrolyte 4
2.2 Oxide coating on NCM cathode 8
2.3 Halide solid-state electrolyte 10
Ⅲ. Experimental 18
3.1 Preparation of materials 18
3.2 Coating approach 18
3.3 Characterization 19
3.4 All-solid-state battery assembly 19
3.5 Electrochemical measurements 20
Ⅳ. Results and discussion 21
4.1 Halide coating on NCM-based cathode active materials 21
4.2 Enhanced rate capability of halide-coated NCM cathode 31
4.3 Interfacial stability of halide-coated NCM in the composite cathode 33
4.4 Chemical composition analysis of composite electrolytes 39
4.5 Electrochemical performance of ASSBs 42
4.6 Preventing side reactions and microstructural degradation via halide coating 44
Ⅴ. Conclusion 46
Reference 47
국문요약문 52
URI
http://hdl.handle.net/20.500.11750/45740

http://dgist.dcollection.net/common/orgView/200000655255
DOI
10.22677/THESIS.200000655255
Degree
Master
Department
Department of Energy Science and Engineering
Publisher
DGIST
Related Researcher
  • 이종원 Lee, Jong-Won
  • Research Interests 이차전지; 연료전지; 재료전기화학; 나노에너지소재
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Department of Energy Science and Engineering Theses Master

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