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Synthesis and application of CdxHg1-xX based quantum dots with high quantum yield infrared photoluminescence
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dc.contributor.advisor 최종민 -
dc.contributor.author Gyudong Lee -
dc.date.accessioned 2023-09-18T21:00:45Z -
dc.date.available 2023-09-18T21:00:45Z -
dc.date.issued 2023 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/46403 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000686731 -
dc.description Infrared; Quantum dot; Photoluminescence quantum yield; Ripening reaction; Deep-tissue imaging -
dc.description.tableofcontents I. Introduction 1
1.1. QDs as NIR emitter 1
1.2. Various NIR emission QDs 3
1.2.1. Cd and Hg based QDs 3
1.2.2. Pb based QDs 3
1.2.3. In based QDs 4
1.2.4. Ag based QDs 4
1.2.5. Cu based QDs 5
1.3 Synthesis method of QDs 6
1.3.1. Hot-injection method 6
1.3.2. Heat-up method 7
1.3.3. Cation exchange 7
1.3.4. Shell overcoating 9
1.4. Summary 11
1.5 References 12
II. Design and synthesis of CdHgSe/HgS/CdZnS core/multi-shell quantum dots exhibiting high-quantum-yield tissue-penetrating shortwave infrared luminescence 19
2.1 Introduction 19
2.2 Results and discussion 21
2.2.1 Design of high-QY SWIR QDs 21
2.2.2 Synthesis of high-QY SWIR QDs 22
2.2.3 Preparation and surface structure of stable CdxHg1-xSe alloy QDs 24
2.2.4 Ligand-dependent thermodynamics of Cd-Hg cation exchange reactions 25
2.2.5 Structural characterization of high-QY SWIR QDs 27
2.2.6 Luminescence of aqueous- and polymer-soluble SWIR QDs 28
2.2.7 Quantitative deep-tissue SWIR imaging using SWIR QD/IP-L composites 29
2.3. Conclusion 34
2.4. Experimental section 35
2.5. References 44
III. Facile synthesis of giant CdHgSe/Cd(Hg)SeS core/shell quantum dots with large-Stokes-shift high-quantum-yield near-infrared photoluminescence via chlorine-mediated ripening 79
3.1 Introduction 79
3.2 Results and discussion 81
3.2.1 Synthesis of giant CdHgSe/Cd(Hg)SeS core/shell QDs via chlorine-mediated ripening 81
3.2.2 Characterization of optical properties of giant CdHgSe/Cd(Hg)SeS core/shell QDs 81
3.2.3 Characterization of structural properties of giant CdHgSe/Cd(Hg)SeS core/shell QDs 82
3.2.4 Mass analysis of giant CdHgSe/Cd(Hg)SeS core/shell QDs synthesis reaction product 83
3.2.5 Blinking properties of giant CdHgSe/Cd(Hg)SeS QD 84
3.3. Conclusion 86
3.4. Experimental section 87
3.5. References 92
Summary in Korean 103
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dc.format.extent 104 -
dc.language eng -
dc.publisher DGIST -
dc.title Synthesis and application of CdxHg1-xX based quantum dots with high quantum yield infrared photoluminescence -
dc.title.alternative 높은 적외선 광발광 양자효율을 가지는 CdxHg1-xX 기반 양자점의 합성 및 응용 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000686731 -
dc.description.degree Doctor -
dc.contributor.department Department of Energy Science and Engineering -
dc.identifier.bibliographicCitation Gyudong Lee. (2023). Synthesis and application of CdxHg1-xX based quantum dots with high quantum yield infrared photoluminescence. doi: 10.22677/THESIS.200000686731 -
dc.contributor.coadvisor Sung Jun Lim -
dc.date.awarded 2023-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.ED 이16 202308 -
dc.date.accepted 2023-09-14 -
dc.contributor.alternativeDepartment 에너지공학과 -
dc.subject.keyword Infrared -
dc.subject.keyword Quantum dot -
dc.subject.keyword Photoluminescence quantum yield -
dc.subject.keyword Ripening reaction -
dc.subject.keyword Deep-tissue imaging -
dc.contributor.affiliatedAuthor Gyudong Lee -
dc.contributor.affiliatedAuthor Jongmin Choi -
dc.contributor.affiliatedAuthor Sung Jun Lim -
dc.contributor.alternativeName 이규동 -
dc.contributor.alternativeName Jongmin Choi -
dc.contributor.alternativeName 임성준 -
dc.rights.embargoReleaseDate 2026-08-31 -
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