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dc.contributor.advisor 정낙천 -
dc.contributor.author Yeongjin Son -
dc.date.accessioned 2023-09-18T21:00:52Z -
dc.date.available 2023-09-18T21:00:52Z -
dc.date.issued 2023 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/46413 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000685582 -
dc.description Metalloenzyme; Biomimetic chemistry; Cobalt-dioxygen intermediates; Aldehyde deformylation; Nitrile activation; Mechanism study -
dc.description.tableofcontents Contents

Abstract i

General Introduction 1

Chapter 1. Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate 13
1.1. Abstract 13
1.2. Introduction 14
1.3. Results and Discussion 17
1.4. Conclusion 69
1.5. Experimental Section 70
1.6. References 78

Chapter 2. Mechanistic Insights into Nitrile Activation by Cobalt(III)-Hydroperoxo Intermediates: The Influence of Ligand Basicity 85
2.1. Abstract 85
2.2. Introduction 87
2.3. Results and Discussion 90
2.4. Conclusion 127
2.5. Experimental Section 128
2.6. References 136

Concluding Remarks 147
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dc.format.extent 149 -
dc.language eng -
dc.publisher DGIST -
dc.title Mechanistic Insights in Oxidative Reactions of Biomimetic Cobalt-Dioxygen Intermediates -
dc.title.alternative 생체모방 코발트-이산소 중간체들의 산화반응에서의 메커니즘적 이해 -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000685582 -
dc.description.degree Doctor -
dc.contributor.department Department of Physics and Chemistry -
dc.contributor.coadvisor Jaeheung Cho -
dc.date.awarded 2023-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.MD 손64 202308 -
dc.date.accepted 2023-09-14 -
dc.contributor.alternativeDepartment 화학물리학과 -
dc.subject.keyword Metalloenzyme -
dc.subject.keyword Biomimetic chemistry -
dc.subject.keyword Cobalt-dioxygen intermediates -
dc.subject.keyword Aldehyde deformylation -
dc.subject.keyword Nitrile activation -
dc.subject.keyword Mechanism study -
dc.contributor.affiliatedAuthor Yeongjin Son -
dc.contributor.affiliatedAuthor Nak Cheon Jeong -
dc.contributor.affiliatedAuthor Jaeheung Cho -
dc.contributor.alternativeName 손영진 -
dc.contributor.alternativeName Nak Cheon Jeong -
dc.contributor.alternativeName 조재흥 -
dc.rights.embargoReleaseDate 2028-08-31 -
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