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dc.contributor.advisor 상가라주 샨무감 -
dc.contributor.author Yaerin Lee -
dc.date.accessioned 2023-09-18T21:01:07Z -
dc.date.available 2023-09-18T21:01:07Z -
dc.date.issued 2023 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/46432 -
dc.identifier.uri http://dgist.dcollection.net/common/orgView/200000687687 -
dc.description Zinc Bromine Redox Flow Batteries; Nitrogen doped carbon; catalyst; Redox reaction; Energy Efficiency -
dc.description.tableofcontents Ⅰ. INTRODUCTION 1
1.1 Energy storage system and flow batteries 1
1.2 Principle and key components of ZBRFB 2
1.3 Current status and challenges of ZBRFB 4
1.4 Development of the Bromine-Side Electrode 7
1.5 Purpose of research 8
Ⅱ. EXPERIMENTAL 10
2.1 Multi-channeled Nitrogen-doped Carbon Nanorods Catalyst for use in improvement of Br2/Br- redox couple 10
2.1.1 Materials 10
2.1.2 Fabrication of N-MCNR 10
2.1.2.1 Electrospinning Synthesis Procedure 11
2.1.2.2 Calcination Synthesis Procedure 11
2.2 Two-Dimensional MXene for Improved Performance in ZBRFB 12
2.2.1 Materials 12
2.2.2 Fabrication of MXene 13
2.3 Electrode Preparation 13
2.3.1 Three electrode system 13
2.3.2 Preparation of modified electrode for battery cell 14
2.3.2.1 Preparation of N-MCNR modified Electrode 14
2.3.2.2 Preparation of MXene modified Electrode 14
2.4 Characterization 15
2.4.1 Structure characterization 15
2.4.2 Chemical characterization 15
2.4.2.1 Elemental Analysis 15
2.4.2.2 X-ray diffractometry 15
2.4.3.3 Raman Analysis 16
2.4.2.4 XPS 16
2.4.3 Physical characterization 16
2.4.3.1 BET 16
2.4.3.2 Contact Angle 16
2.4.4. Electrochemical Analysis 17
2.4.5.ZBRFB Performance 17
Ⅲ. RESULTS AND DISCUSSION 18
3.1 Exploration of Multi-channeled Nitrogen-doped Carbon Nanorods Catalyst for use in improvement of Br2/Br- redox couple 18
3.1.1 Characterization of materials 18
3.1.2 Structural characterization 18
3.1.3 Chemical characterization 21
3.1.4 Physical l characterization 25
3.1.5 Electrochemical Analysis 27
3.1.6 ZBRFB cell performance 30
3.1.7 Summary 33
3.2 Two-Dimensional MXene for Improved Performance in ZBRFB 34
3.2.1 Characterization of materials 34
3.2.2 Physical characterization 35
3.2.3 Chemical characterization 36
3.2.4 Electrochemical Analysis 37
3.2.5 ZBRFB cell performance 39
3.2.6 Post electrode analysis 42
Ⅳ. CONCLUSION 44
Ⅴ.REFERENCES 45
요약문 49
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dc.format.extent 60 -
dc.language eng -
dc.publisher DGIST -
dc.title Development of Electrode Materials for High-Performance Zinc-Bromine Redox Flow Batteries -
dc.type Thesis -
dc.identifier.doi 10.22677/THESIS.200000687687 -
dc.description.degree Master -
dc.contributor.department Department of Energy Science and Engineering -
dc.contributor.coadvisor Hongkyung Lee -
dc.date.awarded 2023-08-01 -
dc.publisher.location Daegu -
dc.description.database dCollection -
dc.citation XT.EM 이64 202308 -
dc.date.accepted 2023-09-14 -
dc.contributor.alternativeDepartment 에너지공학과 -
dc.subject.keyword Zinc Bromine Redox Flow Batteries -
dc.subject.keyword Nitrogen doped carbon -
dc.subject.keyword catalyst -
dc.subject.keyword Redox reaction -
dc.subject.keyword Energy Efficiency -
dc.contributor.affiliatedAuthor Yaerin Lee -
dc.contributor.affiliatedAuthor Sangaraju Shanmugam -
dc.contributor.affiliatedAuthor Hongkyung Lee -
dc.contributor.alternativeName 이예린 -
dc.contributor.alternativeName Sangaraju Shanmugam -
dc.contributor.alternativeName 이홍경 -
dc.rights.embargoReleaseDate 2028-08-31 -
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