Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Somi | - |
dc.contributor.author | Jo, Junhyuk | - |
dc.contributor.author | Lee, Sunggi | - |
dc.contributor.author | Chung, Won-Jin | - |
dc.date.accessioned | 2023-12-13T11:10:21Z | - |
dc.date.available | 2023-12-13T11:10:21Z | - |
dc.date.created | 2023-10-25 | - |
dc.date.issued | 2023-10 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11750/46645 | - |
dc.description.abstract | Previously available ketyl radical cyclization conditions suffer from low and uncontrollable diastereoselectivity because of the absence of reagent-substrate interactions. In this report, stereochemical modulation was accomplished by taking advantage of the pyridine-boryl radical, which leaves the synthetically modifiable boronate moiety on the carbonyl oxygen near the reacting center during the stereo-determining cyclization step. In consequence, a catalytic diastereoselective synthesis of trans-2-substituted-1-indanols was achieved in the presence of a sterically congested six-membered diboronic ester and an efficient hydrogen atom donor. © The Royal Society of Chemistry 2023 | - |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.title | Stereochemical modulation of ketyl radical cyclization enabled by pyridine-boryl radicals: catalytic diastereoselective synthesis of trans-2-alkyl-1-indanols | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/d3cc02248j | - |
dc.identifier.wosid | 001069286500001 | - |
dc.identifier.scopusid | 2-s2.0-85172696752 | - |
dc.identifier.bibliographicCitation | Chemical Communications, v.59, no.80, pp.11983 - 11986 | - |
dc.description.isOpenAccess | FALSE | - |
dc.subject.keywordPlus | DENSITY FUNCTIONALS | - |
dc.subject.keywordPlus | AMINATION | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | KETONES | - |
dc.citation.endPage | 11986 | - |
dc.citation.number | 80 | - |
dc.citation.startPage | 11983 | - |
dc.citation.title | Chemical Communications | - |
dc.citation.volume | 59 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.type.docType | Article | - |
There are no files associated with this item.