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Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect
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dc.contributor.author Derrick, Jeffrey S. ko
dc.contributor.author Kim, Yujeong ko
dc.contributor.author Tak, Hyeon Woo ko
dc.contributor.author Park, Kiyoung ko
dc.contributor.author Cho, Jaeheung ko
dc.contributor.author Kim, Sun Hee ko
dc.contributor.author Lim, Mi Hee ko
dc.date.accessioned 2017-11-20T14:17:31Z -
dc.date.available 2017-11-20T14:17:31Z -
dc.date.created 2017-11-15 -
dc.date.issued 2017-10 -
dc.identifier.citation Dalton Transactions, v.46, no.39, pp.13166 - 13170 -
dc.identifier.issn 1477-9226 -
dc.identifier.uri http://hdl.handle.net/20.500.11750/4704 -
dc.description.abstract Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2. © 2017 The Royal Society of Chemistry. -
dc.publisher Royal Society of Chemistry -
dc.subject 1,4,8,11-Tetramethyl-1,4,8,11-Tetraazacyclotetradecane -
dc.subject Amine Complexes -
dc.subject Anion Effects -
dc.subject Complexes -
dc.subject Computational Analysis -
dc.subject Coordinating Solvents -
dc.subject Copper Compounds -
dc.subject Crystal-Structure -
dc.subject Cyclam Ligands -
dc.subject Diastereoisomers -
dc.subject Electron-Transfer -
dc.subject Isomers -
dc.subject Nickel(II) -
dc.subject Oxoiron(IV) Complex -
dc.subject Perchlorate -
dc.subject Reactivity -
dc.title Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect -
dc.type Article -
dc.identifier.doi 10.1039/c7dt01489a -
dc.identifier.wosid 000412765000002 -
dc.identifier.scopusid 2-s2.0-85031032726 -
dc.type.local Article(Overseas) -
dc.type.rims ART -
dc.identifier.bibliographicCitation Derrick, Jeffrey S. (2017-10). Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect. doi: 10.1039/c7dt01489a -
dc.description.journalClass 1 -
dc.contributor.nonIdAuthor Derrick, Jeffrey S. -
dc.contributor.nonIdAuthor Kim, Yujeong -
dc.contributor.nonIdAuthor Park, Kiyoung -
dc.contributor.nonIdAuthor Kim, Sun Hee -
dc.contributor.nonIdAuthor Lim, Mi Hee -
dc.identifier.citationVolume 46 -
dc.identifier.citationNumber 39 -
dc.identifier.citationStartPage 13166 -
dc.identifier.citationEndPage 13170 -
dc.identifier.citationTitle Dalton Transactions -
dc.type.journalArticle Article -
dc.description.isOpenAccess N -
dc.contributor.affiliatedAuthor Tak, Hyeon Woo -
dc.contributor.affiliatedAuthor Cho, Jaeheung -
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