Title

Light-Responsive Metal-Organic Materials for Photocatalysis and Photothermal Conversion

DGIST Authors

Bongkyeom Kim ; Jinhee Park ; Seonki Hong

Advisor

박진희

Co-Advisor(s)

Seonki Hong

Issued Date

2024

Awarded Date

2024-02-01

Citation

Bongkyeom Kim. (2024). Light-Responsive Metal-Organic Materials for Photocatalysis and Photothermal Conversion. doi: 10.22677/THESIS.200000727952

Type

Thesis

Description

Metal-organic materials; Metal-organic gel; Metal-organic framework; Photocatalyst; Photothermal conversion

Table Of Contents

List of Contents
Abstract i
List of Contents iii
List of Tables v
List of Figures vii
List of Publications xvii

Chapter Ⅰ. Introduction 1
1.1. Light-Responsive Materials 1
1.2. Metal-Organic Gels 2
1.3. Metal-Organic Frameworks 5

Chapter ⅠI. Stimuli-Responsive Ti-Organic Gels and Aerogels Derived from Ti-Oxo Clusters:
Hierarchical Porosity and Photocatalytic Activity 8
2.1. Abstract 8
2.2. Introduction 10
2.3. Results and discussion 13
2.4. Conclusion 54
2.5. Experimental section 55

Chapter ⅠII. π-Stacks of Radical-Anionic Naphthalenediimides in a Metal-Organic Framework 65
3.1. Abstract 65
3.2. Introduction 67
3.3. Results and discussion 76
3.4. Conclusion 102
3.5. Experimental section 103

Chapter ⅠV. Isostructural Metal-Organic Frameworks based on the Strong Structure-Directing
π-Dimer of Radical Anion 123
4.1. Abstract 123
4.2. Introduction 124
4.3. Results and discussion 127
4.4. Conclusion 144
4.5. Experimental section 145

Chapter V. Calcium-Porphyrinic Framework as a Biocompatible Photocatalyst 170
5.1. Abstract 170
5.2. Introduction 171
5.3. Results and discussion 175
5.4. Conclusion 186
5.5. Experimental section 187

Chapter VI. Conclusion 195
References 197
Summary (국문요약) 211

URI

http://hdl.handle.net/20.500.11750/48040
http://dgist.dcollection.net/common/orgView/200000727952

DOI

10.22677/THESIS.200000727952

Degree

Doctor

Department

Department of Physics and Chemistry

Publisher

DGIST

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