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Porous Random Aromatic Copolymers for Rapid Removal of Diverse Aromatic Pollutants via Charge Transfer Interactions

Title
Porous Random Aromatic Copolymers for Rapid Removal of Diverse Aromatic Pollutants via Charge Transfer Interactions
Author(s)
Dongjun Lee
DGIST Authors
Dongjun LeeChiyoung ParkJu-Hyuck Lee
Advisor
박치영
Co-Advisor(s)
Ju-Hyuck Lee
Issued Date
2024
Awarded Date
2024-02-01
Type
Thesis
Description
Diverse aromatic pollutants;Mixed ionic dyes;Adsorption;Porous random aromatic copolymers;Charge transfer interactions
Table Of Contents
List of Contents
Abstract i
List of Abbreviations and Symbols ii
List of Contents · iv
List of Tables and Figures v

Ⅰ. Introduction
1.1 Freshwater scarcity 1
1.2 Water pollution · 1
1.3 Aromatic pollutants in water: cationic and anionic dyes · 2
1.4 Adsorption 3
1.4.1 Electrostatic (charge transfer) interactions 3
1.4.2 Hydrogen bonding · 4
1.4.3 π- π interactions· 4
1.4.4 Hydrophobic interactions 4
1.5 Adsorbent · 4
1.5.1 Resorcinol-formaldehyde (RF) resin · 4
1.5.2 Doped benzoquinone-pyrrole (D-BQ-PY) · 5
1.5.3 RF resin/D-BQ-PY complex · 5

Ⅱ. Experimental
2.1 Materials 6
2.2 Instruments and Characterizations 6
2.3 Synthesis of RF resin 6
2.4 Synthesis of BQ-PY · 6
2.5 Synthesis of D-BQ-PY · 7
2.6 Batch adsorption test 7
2.7 Regeneration test 7

Ⅲ. Results and Discussion
3.1 Structures and chemical properties 10
3.2 Adsorption performance 13
Ⅳ. Conclusion · 21
Ⅴ. References 22
Ⅵ. Korean Summary 28


List of Tables and Figures
Figure 1.1 1
Figure 1.2 2
Figure 1.3 3
Figure 2.1 8
Figure 2.2 8
Scheme 3 9
Figure 3.1 · 10
Figure 3.2 · 11
Figure 3.3 · 11
Figure 3.4 · 13
Figure 3.5 · 14
Figure 3.6 · 14
Figure 3.7 · 15
Figure 3.8 · 15
Table 3.1 16
Table 3.2 16
Figure 3.9 · 16
Figure 3.10 17
Figure 3.11 18
Table 3.3 19
Figure 3.12 19
URI
http://hdl.handle.net/20.500.11750/48091

http://dgist.dcollection.net/common/orgView/200000724011
DOI
10.22677/THESIS.200000724011
Degree
Master
Department
Department of Energy Science and Engineering
Publisher
DGIST
Related Researcher
  • 박치영 Park, Chiyoung
  • Research Interests Soft Conductors; Conducting Polymers; Carbon Materials; Renewable energy materials;
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Department of Energy Science and Engineering Theses Master

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