Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.advisor | 정병혁 | - |
| dc.contributor.author | Yurim Lee | - |
| dc.date.accessioned | 2024-02-29T21:02:41Z | - |
| dc.date.available | 2024-02-29T21:02:41Z | - |
| dc.date.issued | 2024 | - |
| dc.identifier.uri | http://hdl.handle.net/20.500.11750/48119 | - |
| dc.identifier.uri | http://dgist.dcollection.net/common/orgView/200000724550 | - |
| dc.description | Silylation;Allene;PhMe2SiBpin;2-Silyl-1;3-butadienes;Allylsilanes | - |
| dc.description.tableofcontents | ABSTRACT i LIST OF CONTENTS ii Ⅰ. INTRODUCTION 1.1 Backgrounds 1 1.2 Previous reports 1.2.1 Preparation of 2-silyl-1,3-butadienes 1 1.2.2 Preparation of allylsilanes 3 1.3 Our strategy 4 II. RESULT AND DISCUSSIONS 2.1 Optimization of reaction conditions 2.1.1 Preparation of 2-silyl-1,3-butadiene 5 2.1.2 Preparation of (Z)-allylsilane 8 2.2 Substrate scopes 2.2.1 2-Silyl-1,3-butadienes with 2° allenols 10 2.2.2 2-Silyl-1,3-butadienes with other allenols 12 2.2.3 (Z)-Allylsilanes with mono-substituted allenes 13 2.3 Reaction mechanisms 2.3.1 Proposed catalytic cycle of 2-silyl-1,3-butadienes formation 14 2.3.2 Proposed catalytic cycle of allylsilanes formation 15 2.4 Synthetic applications of 2-silyl-1,3-butadienes 16 III. CONCLUSION 17 IV. EXPERIMENTAL SECTION 18 REFERENCE 49 국문 요약문 52 |
- |
| dc.format.extent | 59 | - |
| dc.language | eng | - |
| dc.publisher | DGIST | - |
| dc.title | Studies on Development of Cu-Catalyzed Silyl Addition to Allenes | - |
| dc.type | Thesis | - |
| dc.identifier.doi | 10.22677/THESIS.200000724550 | - |
| dc.description.degree | Master | - |
| dc.contributor.department | Department of Physics and Chemistry | - |
| dc.contributor.coadvisor | Sunggi Lee | - |
| dc.date.awarded | 2024-02-01 | - |
| dc.publisher.location | Daegu | - |
| dc.description.database | dCollection | - |
| dc.citation | XT.MM이66 202402 | - |
| dc.date.accepted | 2024-01-30 | - |
| dc.contributor.alternativeDepartment | 화학물리학과 | - |
| dc.subject.keyword | Silylation | - |
| dc.subject.keyword | Allene | - |
| dc.subject.keyword | PhMe2SiBpin | - |
| dc.subject.keyword | 2-Silyl-1 | - |
| dc.subject.keyword | 3-butadienes | - |
| dc.subject.keyword | Allylsilanes | - |
| dc.contributor.affiliatedAuthor | Yurim Lee | - |
| dc.contributor.affiliatedAuthor | Byunghyuck Jung | - |
| dc.contributor.affiliatedAuthor | Sunggi Lee | - |
| dc.contributor.alternativeName | 이유림 | - |
| dc.contributor.alternativeName | Byunghyuck Jung | - |
| dc.contributor.alternativeName | 이성기 | - |
| dc.rights.embargoReleaseDate | 2025-02-28 | - |
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