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We report specific heat capacity measurements on a LiFeAs single crystal at temperatures down to 400 mK and magnetic fields up to 9 T. A small specific heat jump at T c and finite residual density of states at T=0 K in the superconducting (SC) state indicate that there are strong unitary scatterers that lead to states within the SC gap. A sublinear magnetic field dependence of the Sommerfeld coefficient γ(H) at T=0 K is equally well fitted by both a nodal d-wave gap as well as a sign changing multiband s ±-wave gap. When impurity effects are taken into account, however, the linear temperature dependence of the electronic specific heat C el/T at low temperatures argues against a nodal d-wave superconducting gap. We conclude that the SC state of LiFeAs is most compatible with the multiband s ±-wave SC state with the gap values Δ small=0. 46Δ large. © 2012 American Physical Society.
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