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Assessing photocatalytic activity using methylene blue without dye sensitisation

Title
Assessing photocatalytic activity using methylene blue without dye sensitisation
Authors
Lee, Soo KeunMills, AndrewWells, Nathan
DGIST Authors
Lee, Soo Keun
Issue Date
ACCEPT
Citation
Catalysis Today
Type
Article
Article Type
Article in Press
Keywords
Cadmium sulfidePhotobleachingPhotocatalysisPhotocatalystsPhotolysisPhotosensitizersSulfur compoundsTitanium dioxideAction spectraDiffuse reflectance spectrumDye sensitisationLeuco methylene blueMethylene BluePhotocatalytic activitiesSemiconductor photocatalystSemiconductor powdersAromatic compounds
ISSN
0920-5861
Abstract
The anaerobic photocatalysed reduction of methylene blue, MB, by glycerol to leuco methylene blue, LMB, is studied using UV-absorbing, P25 TiO2, and visible-absorbing, CdS, semiconductor powder particles as the photosensitizer. In both cases, the photo-reductive bleaching of the dye to LMB, is very rapid, typically <2min. The photobleaching of the MB is readily and simply reversed in the dark by allowing air into the system, so as to let the ambient oxygen to oxidise the photogenerated LMB back to its original blue, oxidized form, MB. Action spectra are recorded for both systems and reveal no evidence of dye-sensitisation, nor dye photolysis over the time scale of the reaction (i.e. ca. 2min). Instead, the action spectra exhibit spectral profiles that match very well that of the diffuse reflectance spectra of the respective semiconductor photocatalysts. The MB/glycerol system appears to offer a simple, quick, unambiguous way to assess the photocatalytic activity of both visible and UV absorbing photocatalyst powders using a dye, such as MB. © 2017 Elsevier B.V.
URI
http://hdl.handle.net/20.500.11750/5587
DOI
10.1016/j.cattod.2017.11.011
Publisher
Elsevier B.V.
Related Researcher
  • Author Lee, Soo Keun  
  • Research Interests Nano material, photocatalyst, TiO2, ZnO
Files:
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Collection:
Smart Textile Convergence Research Group1. Journal Articles


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